Optical, thermal, and electrical analysis of perovskite solar cell with grated cds and embedded plasmonic Au nanoparticles

Abstract

We propose a novel approach to enhance the performance of perovskite solar cells (PSCs) by incorporating grated Cadmium Sulfide (CdS) and plasmonic gold nanoparticles (Au NPs) into the absorber layer. The CdS grating acts as the electron transport layer and penetrates into the perovskite absorber layer, increasing the absorption of the active layer and reducing the electron–hole recombination rate. The plasmonic Au NPs enhance the absorption in the infrared region by scattering and trapping the incident light. We perform a coupled optical and electrical study that shows a significant improvement in the short circuit current density ( JSC ) and power conversion efficiency (PCE) of the PSC after introducing the CdS grating and plasmonic Au NPs. Specifically, we observe a 48% increase in average optical absorption from 800 nm to 1400 nm and a 7.42 mA cm⁻² increase in J SC . We also find that the PCE of the PSC is increased by 7.91% when comparing the planar reference structure (without the CdS grating and the plasmonic Au NP). However, metal nanoparticles introduce ohmic losses and temperature rise in the solar cell. We analyze the non-radiative heat profile, electric field distribution, and temperature distribution across the PSC. We observe a temperature increase of approximately 14 K above the ambient temperature for the grated CdS layer with incorporated Au NPs, which is comparable to the temperature increase observed in the planar reference structure. Our results have the potential to pave the way for the development of highly efficient and stable PSCs in the future.