The Study on Flow Field Simulation and WC-12Co Multi-layer Coating Growth in High-Velocity Oxygen-Fuel (HVOF) Thermal Spraying

IF 3.2 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Journal of Thermal Spray Technology Pub Date : 2024-02-28 DOI:10.1007/s11666-024-01724-4
Chang Li, Siyu Li, Xing Han
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Abstract

HVOF has unique advantages as spraying metal carbides and alloys and is widely used in the aerospace, national defense industry, iron and steel metallurgy, petrochemical industry and other fields. The WC-Co coating prepared by HVOF has the characteristics of low oxide content, high bonding strength, low porosity and high temperature resistance and is the most ideal surface strengthening technology to replace surface chrome plating. In this study, a three-dimensional model of HVOF spraying was established and the flame flow characteristics in the spraying were analyzed. Combined with the discrete phase model (DPM), the influence of spraying distance, particle size and O/F ratio on temperature and velocity for particle flight were revealed. Based on the birth and death unit method, a three-dimensional thermodynamic coupling model of multi-layer coating growth was established. The stress-strain law of each coating unit in the growth process of WC-12Co coating was explored. The optimal particle parameters were obtained by calculating the flow field. The calculation shows that the optimal temperature and velocity of the sprayed particles are 1402 K and 535 m/s, respectively. The temperature of each coating unit gradually increases from the center to the outer ring and decreases under the action of air cooling with the spread time. The difference of temperature is obvious between the coating and the substrate, resulting in a relatively large stress value at the junction of the two and a relatively concentrated stress between adjacent elements. The maximum tensile stress in the X-axis direction reaches 1908 MPa and distributes in an elliptical shape at the center position of the coating unit. The shear stress in the XY direction is concentrated at the edge of each element for the coating, and the maximum reaches 1285 MPa.

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高速氧气-燃料 (HVOF) 热喷涂中的流场模拟与 WC-12Co 多层涂层生长研究
HVOF 具有喷涂金属碳化物和合金的独特优势,广泛应用于航空航天、国防工业、钢铁冶金、石油化工等领域。HVOF 制备的 WC-Co 涂层具有氧化物含量低、结合强度高、孔隙率低、耐高温等特点,是替代表面镀铬的最理想的表面强化技术。本研究建立了 HVOF 喷射的三维模型,分析了喷射过程中的火焰流动特性。结合离散相模型(DPM),揭示了喷射距离、颗粒大小和 O/F 比对颗粒飞行温度和速度的影响。基于生灭单元法,建立了多层涂层生长的三维热力学耦合模型。探讨了 WC-12Co 涂层生长过程中各涂层单元的应力应变规律。通过计算流场得到了最佳粒子参数。计算结果表明,喷涂颗粒的最佳温度和速度分别为 1402 K 和 535 m/s。每个涂层单元的温度从中心向外圈逐渐升高,并随着扩散时间的延长在空气冷却的作用下逐渐降低。涂层与基体之间的温差明显,导致两者交界处的应力值相对较大,相邻元素之间的应力相对集中。X 轴方向的最大拉伸应力达到 1908 兆帕,在涂层单元中心位置呈椭圆形分布。XY 轴方向上的剪切应力集中在涂层每个元件的边缘,最大值达到 1285 兆帕。
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来源期刊
Journal of Thermal Spray Technology
Journal of Thermal Spray Technology 工程技术-材料科学:膜
CiteScore
5.20
自引率
25.80%
发文量
198
审稿时长
2.6 months
期刊介绍: From the scientific to the practical, stay on top of advances in this fast-growing coating technology with ASM International''s Journal of Thermal Spray Technology. Critically reviewed scientific papers and engineering articles combine the best of new research with the latest applications and problem solving. A service of the ASM Thermal Spray Society (TSS), the Journal of Thermal Spray Technology covers all fundamental and practical aspects of thermal spray science, including processes, feedstock manufacture, and testing and characterization. The journal contains worldwide coverage of the latest research, products, equipment and process developments, and includes technical note case studies from real-time applications and in-depth topical reviews.
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