S. V. Kuznetsov, V. A. Konyushkin, A. N. Nakladov, P. A. Popov, A. A. Pynenkov, K. N. Nishchev, A. A. Alexandrov
{"title":"Thermophysical Characteristics of Single Crystals of Ba1 – x – yYbxRyF2 + x + y (R = Tm, Ho) Solid Solutions","authors":"S. V. Kuznetsov, V. A. Konyushkin, A. N. Nakladov, P. A. Popov, A. A. Pynenkov, K. N. Nishchev, A. A. Alexandrov","doi":"10.1134/S0020168523110080","DOIUrl":null,"url":null,"abstract":"<p>Single crystals of Ba<sub>1 –</sub> <sub><i>x</i></sub> <sub>–</sub> <sub><i>y</i></sub>Yb<sub><i>x</i></sub>R<sub><i>y</i></sub>F<sub>2 +</sub> <sub><i>x</i></sub> <sub>+</sub> <sub><i>y</i></sub> (R = Tm, Ho) solid solutions have been grown by the Bridgman technique in vacuum using a CF<sub>4</sub> fluorination atmosphere. We have measured their thermal conductivity in the range 50–300 K and their refractive index from the visible to IR spectral region. As the ytterbium content increases from 2 to 14 mol %, the room-temperature thermal conductivity of the solid solutions with R = Tm and Ho decreases from 3.39 to 1.18 and from 3.11 to 1.18 W/(m K), respectively. Raising the holmium and thulium content of the solid solutions leads to a gradual increase in their refractive index, and it gradually decreases with increasing wavelength.</p>","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"59 11","pages":"1267 - 1274"},"PeriodicalIF":0.9000,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S0020168523110080","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Single crystals of Ba1 –x–yYbxRyF2 +x+y (R = Tm, Ho) solid solutions have been grown by the Bridgman technique in vacuum using a CF4 fluorination atmosphere. We have measured their thermal conductivity in the range 50–300 K and their refractive index from the visible to IR spectral region. As the ytterbium content increases from 2 to 14 mol %, the room-temperature thermal conductivity of the solid solutions with R = Tm and Ho decreases from 3.39 to 1.18 and from 3.11 to 1.18 W/(m K), respectively. Raising the holmium and thulium content of the solid solutions leads to a gradual increase in their refractive index, and it gradually decreases with increasing wavelength.
期刊介绍:
Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.