Investigating the Effect of ABS on the Mechanical Properties, Morphology, Printability, and 4D Printing of PETG-ABS Blends

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-03-13 DOI:10.1002/mame.202400038
Kiandokht Mirasadi, Davood Rahmatabadi, Ismaeil Ghasemi, Mohammad Khodaei, Majid Baniassadi, Mostafa Baghani
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Abstract

In this study, Acrylonitrile butadiene styrene (ABS) with three different ratios of 30%, 50%, and 70% is used to enhance the shape memory and mechanical properties of Polyethylene terephthalate glycol (PETG). Additionally, morphology, printability, and dynamic thermomechanical analysis are also examined. The thermal test results show that PETG-ABS compounds have two transition temperatures in the range of 80 and 110 °C, which are related to the components. By changing the weight percentage of PETG from 30 to 70%, three morphologies of matrix-droplet, sea-island, and combination of co-continuous and matrix-droplet are observed. The results of the mechanical properties show an increase in strength with the increase of ABS, which can be justified due to the higher strength of ABS compared to PETG. The highest tensile strength of 32.48 MPa and 15.16% elongation is obtained for PETG-ABS(30-70) and PETG-ABS(70-30), respectively. Due to the better shape memory performance of PETG, PETG-ABS(50-50) and PETG-ABS(70-30) have complete shape recovery, and with the increase of PETG, the shape recovery rate also increased. This diversity in morphology, mechanical properties, and shape memory effect is one of the goals of this research which is well fulfilled.

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研究 ABS 对 PETG-ABS 混合物的机械性能、形态、可印刷性和 4D 印刷的影响
本研究采用 30%、50% 和 70% 三种不同比例的丙烯腈-丁二烯-苯乙烯(ABS)来增强聚对苯二甲酸乙二酯(PETG)的形状记忆和机械性能。此外,还对形貌、可印刷性和动态热机械分析进行了研究。热测试结果表明,PETG-ABS 复合物有两个转变温度,分别在 80 ℃ 和 110 ℃ 之间,这与其中的成分有关。将 PETG 的重量百分比从 30% 改为 70%,可观察到基体-液滴、海岛以及共连续和基体-液滴组合三种形态。机械性能结果表明,随着 ABS 用量的增加,强度也在增加,这是因为与 PETG 相比,ABS 的强度更高。PETG-ABS(30-70) 和 PETG-ABS(70-30)的拉伸强度和伸长率分别为 32.48 兆帕和 15.16%。由于 PETG 具有更好的形状记忆性能,PETG-ABS(50-50) 和 PETG-ABS(70-30)具有完全的形状恢复性,并且随着 PETG 用量的增加,形状恢复率也随之增加。这种形态、机械性能和形状记忆效果的多样性是本研究的目标之一,而这一目标也得到了很好的实现。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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