Recycling of Polyolefins for Multiple Lifecycles

IF 4.6 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Macromolecular Materials and Engineering Pub Date : 2024-03-13 DOI:10.1002/mame.202300421
Megan Matthews, Albert van Reenen
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Abstract

The recycling of polyolefins for multiple life cycles is becoming a legislative requirement in the South African plastics industry. This study shows that this cannot be a blanket requirement for all polyolefins. While HDPE displays good resistance to weathering, the decrease in molecular weight limits the maximum number of life cycles before which the resultant product has lost all integrity. Impact polypropylenes fare much worse during weathering and more than 50% of impact properties are lost within the first 12 months of exposure. The blending of virgin material into degraded material can recover some properties of HDPE but not in the case of impact polypropylenes. The same legislation can therefore not be applied to all plastics and specific targets should depend on polymer composition.

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多生命周期的聚烯烃回收利用
在多个生命周期内回收聚烯烃正在成为南非塑料行业的一项立法要求。这项研究表明,这不可能是对所有聚烯烃的一揽子要求。虽然高密度聚乙烯(HDPE)具有良好的耐候性,但分子量的降低限制了产品在失去所有完整性之前的最大生命周期次数。抗冲击聚丙烯在风化过程中的表现要差得多,50% 以上的抗冲击性能会在暴露的头 12 个月内丧失。在降解材料中掺入原生材料可以恢复高密度聚乙烯的某些性能,但抗冲击聚丙烯则不能。因此,同样的法规不能适用于所有塑料,具体目标应取决于聚合物成分。
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来源期刊
Macromolecular Materials and Engineering
Macromolecular Materials and Engineering 工程技术-材料科学:综合
CiteScore
7.30
自引率
5.10%
发文量
328
审稿时长
1.6 months
期刊介绍: Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)
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