FABRICATION OF A NEW CERAMIC COATING BY ELECTROPHORETIC METHOD FOR GRAPHITE ELECTRODES AT HIGH TEMPERATURE

IF 1.2 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Surface Review and Letters Pub Date : 2024-02-21 DOI:10.1142/s0218625x24500768
ANNA RADUCANU, ALAA A. OMRAN, ENAS R. A‘LWAILY, ABHINAV KUMAR, AHMED ELAWADY
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Abstract

A large part of the cost of steel production in the world is related to the consumption of graphite electrodes. Electrode is the only material that maintains its electrical conductivity at high temperatures, and hence it is used as a conductor of electric current in EAF furnaces. Considering the high costs of graphite electrodes, any action that leads to reducing the consumption of graphite electrode can lead to increasing the productivity of steelmaking operations. In this study and as its novelty, the electrophoretic method was used to generate a ceramic coating for the protection of graphite electrodes. Electrophoretic deposition (EPD) is a two-step process in which charged particles suspended in a suspension move towards the oppositely charged electrode under the influence of an electric field which combine as a dense film on the surface. In the EPD technique, the particle size limit is not very important if a stable suspension is formed and micro and nano-sized particles can be used in this method. The numerical simulation of the thermal contour on the graphite electrode was done in ABAQUS software. Moreover, the surface morphology of graphite samples has been investigated via scanning electron microscopy (SEM). The created coating was a combination of Al2O3 and SiO2, which was placed on the surface of test samples by EPD treatment. The obtained results have the properties of resistance to thermal shock and show the increase in the life of coated graphite samples at different temperatures and times.

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用电泳法在高温下为石墨电极制造新型陶瓷涂层
世界钢铁生产成本的很大一部分与石墨电极的消耗有关。电极是唯一能在高温下保持导电性的材料,因此在电弧炉中被用作电流导体。考虑到石墨电极的高成本,任何能减少石墨电极消耗的措施都能提高炼钢作业的生产率。本研究的新颖之处在于采用电泳法生成陶瓷涂层,以保护石墨电极。电泳沉积(EPD)是一个分两步进行的过程,在这一过程中,悬浮液中的带电粒子在电场的影响下向带相反电荷的电极移动,并在电极表面形成一层致密的薄膜。在 EPD 技术中,如果能形成稳定的悬浮液,颗粒大小的限制并不十分重要,微米级和纳米级颗粒都可用于这种方法。在 ABAQUS 软件中对石墨电极上的热轮廓进行了数值模拟。此外,还通过扫描电子显微镜(SEM)研究了石墨样品的表面形态。制作的涂层是 Al2O3 和 SiO2 的组合,通过 EPD 处理将其置于测试样品表面。研究结果表明,涂层石墨样品具有抗热冲击的特性,并且在不同温度和时间下的寿命都有所延长。
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来源期刊
Surface Review and Letters
Surface Review and Letters 工程技术-物理:凝聚态物理
CiteScore
2.20
自引率
9.10%
发文量
139
审稿时长
4.2 months
期刊介绍: This international journal is devoted to the elucidation of properties and processes that occur at the boundaries of materials. The scope of the journal covers a broad range of topics in experimental and theoretical studies of surfaces and interfaces. Both the physical and chemical properties are covered. The journal also places emphasis on emerging areas of cross-disciplinary research where new phenomena occur due to the presence of a surface or an interface. Representative areas include surface and interface structures; their electronic, magnetic and optical properties; dynamics and energetics; chemical reactions at surfaces; phase transitions, reconstruction, roughening and melting; defects, nucleation and growth; and new surface and interface characterization techniques.
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