{"title":"OPTICAL PROPERTIES AND ANTIBACTERIAL ACTIVITY OF Ni, Mg, AND Fe-DOPED ZnO","authors":"TAREK-DIAB OUNIS, KHAOULA RAHMOUNI, LAMIA AOUAR, MOURAD ZAABAT","doi":"10.1142/s0218625x2450104x","DOIUrl":null,"url":null,"abstract":"<p>In recent years, research on pure ZnO, Ni-doped ZnO, Mg-doped ZnO, and Fe-doped ZnO nanostructures has been gradually progressing to create more effective materials that may be applied in a variety of applications. In this investigation, hydrothermal synthesis was used to create both pure ZnO nanoparticles and ZnO that had been doped with Ni, Mg, and Fe at a concentration of 7%. Before testing the nanostructures’ ability to inhibit harmful bacteria (<i>Bacillus subtilis</i>, <i>Staphylococcus aureus</i>, <i>Escherichia coli</i>, <i>Pseudomonas aeruginosa</i>, and <i>Enterobacter</i> sp.), they were shown to have antibacterial activity. With the use of X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and ultraviolet–visible (UV–Vis), their physicochemical characteristics were initially determined. When Ni, Mg, and Fe are inserted into ZnO, XRD measurements show that the particle size decreases from 28.94<span><math altimg=\"eq-00002.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>nm to 19.96<span><math altimg=\"eq-00003.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>nm. The optical bandgap decreases from 3.17<span><math altimg=\"eq-00004.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>eV to 3.08<span><math altimg=\"eq-00005.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>eV with the least value for Fe/ZnO NPs, according to UV–Vis spectral data, which also shows that the absorption edge changes to higher wavelengths (redshift). This research has produced nanoparticle samples of Ni/ZnO, Mg/ZnO, and Fe/ZnO that, when compared to the pure ZnO sample, show intriguing antibacterial activity.</p>","PeriodicalId":22011,"journal":{"name":"Surface Review and Letters","volume":"68 1","pages":""},"PeriodicalIF":1.2000,"publicationDate":"2024-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Review and Letters","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1142/s0218625x2450104x","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In recent years, research on pure ZnO, Ni-doped ZnO, Mg-doped ZnO, and Fe-doped ZnO nanostructures has been gradually progressing to create more effective materials that may be applied in a variety of applications. In this investigation, hydrothermal synthesis was used to create both pure ZnO nanoparticles and ZnO that had been doped with Ni, Mg, and Fe at a concentration of 7%. Before testing the nanostructures’ ability to inhibit harmful bacteria (Bacillus subtilis, Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Enterobacter sp.), they were shown to have antibacterial activity. With the use of X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and ultraviolet–visible (UV–Vis), their physicochemical characteristics were initially determined. When Ni, Mg, and Fe are inserted into ZnO, XRD measurements show that the particle size decreases from 28.94nm to 19.96nm. The optical bandgap decreases from 3.17eV to 3.08eV with the least value for Fe/ZnO NPs, according to UV–Vis spectral data, which also shows that the absorption edge changes to higher wavelengths (redshift). This research has produced nanoparticle samples of Ni/ZnO, Mg/ZnO, and Fe/ZnO that, when compared to the pure ZnO sample, show intriguing antibacterial activity.
期刊介绍:
This international journal is devoted to the elucidation of properties and processes that occur at the boundaries of materials. The scope of the journal covers a broad range of topics in experimental and theoretical studies of surfaces and interfaces. Both the physical and chemical properties are covered. The journal also places emphasis on emerging areas of cross-disciplinary research where new phenomena occur due to the presence of a surface or an interface. Representative areas include surface and interface structures; their electronic, magnetic and optical properties; dynamics and energetics; chemical reactions at surfaces; phase transitions, reconstruction, roughening and melting; defects, nucleation and growth; and new surface and interface characterization techniques.