Modeling the Gas Permeability of the Powder Bed in a Rotary Furnace

IF 0.9 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Powder Metallurgy and Metal Ceramics Pub Date : 2024-03-16 DOI:10.1007/s11106-024-00401-z
A. L. Maximenko, O. I. Hetman, M. B. Shtern, E. A. Olevsky
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Abstract

Rotary furnaces are used as reactors to intensify chemical processes between the powder and gas atmosphere around it. The furnace rotation leads to relative motion and dilation of the powder layers, facilitating gas access. The paper is devoted to the modeling of nickel oxide powder behavior in a rotary furnace to estimate the contribution of furnace rotation speed to gas permeability when the nickel oxide granules are reduced in a hydrogen atmosphere. Discrete element modeling of powder granules in a rotary furnace was conducted employing Altair EDEM commercial software to estimate the powder gas permeability at different stages. The powder bed in a horizontal cylindrical rotary furnace was modeled as a packing of identical spherical granules with diameters equal to those of the nickel oxide granules. The furnace rotation led to periodic oscillations of the powder along the furnace wall with an amplitude that gradually diminished to some steady value. Gas permeability of the powder bed was evaluated through the porosity function, derived from the Carman permeability equations. Greater gas permeability resulting from significant powder dilation was observed only in active shear zones on the powder bed surface and in the contact area between the powder and the furnace wall. Sizes of the shear zones depended on the furnace rotation speed but never exceeded several granule diameters for all rotation speeds. The efficiency of a rotary furnace as a chemical reactor was shown to be determined not only by the powder dilation but also by the regeneration rate for the powder bed surface. The regeneration rate can be calculated and changes nonlinearly with the furnace rotation speed.

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旋转炉中粉末床的气体渗透性建模
回转炉用作反应器,用于强化粉末与周围气体环境之间的化学过程。回转炉的旋转会导致粉末层的相对运动和扩张,从而有利于气体的进入。本文主要研究氧化镍粉末在回转炉中的行为建模,以估算氧化镍颗粒在氢气环境中还原时,回转炉转速对气体渗透性的影响。利用 Altair EDEM 商业软件对旋转炉中的粉末颗粒进行了离散元素建模,以估算不同阶段的粉末气体渗透性。水平圆柱形旋转炉中的粉末床被模拟为直径与氧化镍颗粒相同的球形颗粒堆积。熔炉旋转导致粉末沿炉壁周期性摆动,摆动幅度逐渐减小到某个稳定值。粉末床的气体渗透性是通过孔隙度函数进行评估的,孔隙度函数由卡曼渗透性方程得出。只有在粉末床表面的活动剪切区和粉末与炉壁的接触区域,才能观察到粉末显著扩张导致的气体渗透性增大。剪切区的大小取决于回转炉的转速,但在所有转速下都不会超过几个颗粒直径。事实证明,旋转炉作为化学反应器的效率不仅取决于粉末扩张,还取决于粉末床表面的再生率。再生率是可以计算出来的,并随回转窑转速的变化而非线性变化。
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来源期刊
Powder Metallurgy and Metal Ceramics
Powder Metallurgy and Metal Ceramics 工程技术-材料科学:硅酸盐
CiteScore
1.90
自引率
20.00%
发文量
43
审稿时长
6-12 weeks
期刊介绍: Powder Metallurgy and Metal Ceramics covers topics of the theory, manufacturing technology, and properties of powder; technology of forming processes; the technology of sintering, heat treatment, and thermo-chemical treatment; properties of sintered materials; and testing methods.
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