Synthesis and characterization of nanocarbon from waste batteries via an eco-friendly method

Maraim Kh. Uoda, Hussein Q. Hussein, Rana R. Jalil
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Abstract

The widespread use of disposable batteries to power common electronic devices is a major source of e-waste. There are growing environmental and health concerns due to the expansion of e-waste around the world. Hence, developing a reliable system for recycling old batteries has reached the top of the recycling priority list. The current study presents a novel approach to synthesis carbon nanoparticles (CNPs) from spent batteries via an eco-friendly method that offers economical, environment-friendly, and nontoxic approaches in comparison to conventional chemical methods. The synthesized nanoparticles were characterized by field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX), powder X-ray diffractometry (XRD), UV–VIS absorption analysis (UV), Fourier transform infrared spectroscopy (FT-IR), Atomic force microscope (AFM), and thermo-gravimetric analysis (TGA). The average diameter of the synthesized particles was 40.16 nm, and the particles tended to be aspherical in shape. EDX analysis also predicted the presence of pure carbon, with some contamination arrived at 15% (in weight). This is a novel study in which nanocarbons were synthesized in a brine (7600×10−6) from a target (CNPs>75 nm), which paves the way for future use of CNPs derived from spent batteries and helps the environment by decreasing the amount of electronic waste dumped in landfills.

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用环保方法从废电池中合成纳米碳并确定其特性
广泛使用一次性电池为普通电子设备供电是电子垃圾的一个主要来源。由于电子垃圾在全球范围内的不断扩大,人们对环境和健康的担忧与日俱增。因此,开发一种可靠的旧电池回收系统已成为回收的首要任务。本研究提出了一种从废旧电池中合成碳纳米粒子(CNPs)的新方法,与传统化学方法相比,该方法具有经济、环保和无毒的特点。合成的纳米颗粒通过场发射扫描电子显微镜(FE-SEM)、能量色散 X 射线(EDX)、粉末 X 射线衍射仪(XRD)、紫外可见吸收分析(UV)、傅立叶变换红外光谱(FT-IR)、原子力显微镜(AFM)和热重分析(TGA)进行了表征。合成颗粒的平均直径为 40.16 nm,颗粒形状趋于非球面。EDX 分析还预测了纯碳的存在,部分污染达到 15%(重量百分比)。这是一项在盐水(7600×10-6)中从目标物(CNPs>75 nm)合成纳米碳的新颖研究,它为将来使用从废电池中提取的 CNPs 铺平了道路,并通过减少倾倒在垃圾填埋场的电子废物数量来保护环境。
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