{"title":"Enthalpy and heat capacity of liquid Na15Pb4 and Na50Pb50 alloys","authors":"A. R. Khairulin, S. V. Stankus","doi":"10.1134/S0869864323060185","DOIUrl":null,"url":null,"abstract":"<div><p>Using an isothermal drop calorimeter, the enthalpy increment of the Na<sub>15</sub>Pb<sub>4</sub> and Na<sub>50</sub>Pb<sub>50</sub> alloys was measured and the heat capacity was determined in the temperature range of 420–1075 K, including the solid and liquid states. It has been established that the values of the heat capacity of melts significantly exceed the calculations of this value according to the laws for an ideal solution, and this difference decreases with increasing temperature. The obtained results confirm the currently existing ideas that various complexes with a partially ionic character of the interatomic interaction are formed in the melts of alkali metals with lead systems.</p></div>","PeriodicalId":800,"journal":{"name":"Thermophysics and Aeromechanics","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thermophysics and Aeromechanics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0869864323060185","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, AEROSPACE","Score":null,"Total":0}
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Abstract
Using an isothermal drop calorimeter, the enthalpy increment of the Na15Pb4 and Na50Pb50 alloys was measured and the heat capacity was determined in the temperature range of 420–1075 K, including the solid and liquid states. It has been established that the values of the heat capacity of melts significantly exceed the calculations of this value according to the laws for an ideal solution, and this difference decreases with increasing temperature. The obtained results confirm the currently existing ideas that various complexes with a partially ionic character of the interatomic interaction are formed in the melts of alkali metals with lead systems.
期刊介绍：
The journal Thermophysics and Aeromechanics publishes original reports, reviews, and discussions on the following topics: hydrogasdynamics, heat and mass transfer, turbulence, means and methods of aero- and thermophysical experiment, physics of low-temperature plasma, and physical and technical problems of energetics. These topics are the prior fields of investigation at the Institute of Thermophysics and the Institute of Theoretical and Applied Mechanics of the Siberian Branch of the Russian Academy of Sciences (SB RAS), which are the founders of the journal along with SB RAS. This publication promotes an exchange of information between the researchers of Russia and the international scientific community.
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