{"title":"The Difunctionalization of Alkenes Completed by DMTSM and CF3SO2Na without Metal Catalysts","authors":"Siwei Shen, Jinzhao Gao, Xiaofeng Luo, Tianqiang Wang, Peihua Liu, Rulong Yan","doi":"10.1055/a-2283-5928","DOIUrl":null,"url":null,"abstract":"<p>The electrophilic thiolation of alkenes initiated by DMTSM and the addition of CF<sub>3</sub>SO<sub>2</sub>Na in one pot has been developed. This reaction also can be extended to ArSO<sub>2</sub>Na. This protocol features a good substrate scope, simple procedures, and mild reaction conditions and affords the desired products in moderate yields without metal catalysts.</p> ","PeriodicalId":22319,"journal":{"name":"Synlett","volume":"144 1","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2024-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synlett","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1055/a-2283-5928","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
The electrophilic thiolation of alkenes initiated by DMTSM and the addition of CF3SO2Na in one pot has been developed. This reaction also can be extended to ArSO2Na. This protocol features a good substrate scope, simple procedures, and mild reaction conditions and affords the desired products in moderate yields without metal catalysts.
期刊介绍：
SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
