Preparation of Nebula-like Polysiloxane/Silica Superhydrophobic Composite Microspheres Controlled by Density Method

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series B Pub Date : 2024-03-23 DOI:10.1134/s156009042460013x
Xiaoling Huang, Bodong Wang, Yifan Liu, Le Liu, Wentong Yang, Yan Jiang, Hongwen Zhang
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Abstract

In this study, flower-shaped nano-silica was prepared through a calcination method, and then modified. Then using the method of free radical polymerization, and polysiloxane composite compounded with siloxane. The prepared composite microspheres combined the stability of polysiloxane with the unique surface morphology of flower-shaped nano-silica. The relative density of the composite material was controlled by the significant difference in density between siloxane microspheres and nano-silica. The structure and morphology of the composite microspheres were characterized and analyzed using FTIR, SEM, and other tests. The results showed successful compounding of siloxane and nano-silica, resulting in superhydrophobic polysiloxane/nano-SiO2 composite microspheres with a water contact angle of 152°. The composite microspheres exhibited a nebula-like overall structure.

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用密度法制备星云状聚硅氧烷/二氧化硅超疏水复合微球
摘要 本研究通过煅烧法制备了花形纳米二氧化硅,并对其进行了改性。然后采用自由基聚合的方法,与聚硅氧烷进行复合。制备的复合微球结合了聚硅氧烷的稳定性和花形纳米二氧化硅独特的表面形态。硅氧烷微球和纳米二氧化硅的密度差异显著,从而控制了复合材料的相对密度。利用傅立叶变换红外光谱、扫描电镜和其他测试对复合微球的结构和形态进行了表征和分析。结果表明,硅氧烷和纳米二氧化硅的成功复合,产生了超疏水聚硅氧烷/纳米二氧化硅复合微球,其水接触角为 152°。复合微球的整体结构呈星云状。
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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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