Synthesis, Structure, and Thermoelectric Properties of Holmium-Doped Nanomaterials Based on Bismuth Telluride

IF 0.8 Q3 Engineering Nanotechnologies in Russia Pub Date : 2023-12-01 DOI:10.1134/s2635167623600980
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Abstract

Powdered thermoelectric materials Bi2–xHoxTe2.7Se0.3 (x = 0, 0.001, 0.0025, 0.005, 0.01, and 0.02) are obtained by the method of solvothermal synthesis. The possibility of obtaining nanomaterials based on holmium-doped bismuth telluride is shown. The influence of the concentration of holmium on the parameters of the crystal lattice, morphology and average size of the synthesized particles are studied. Bulk materials Bi2–xHoxTe2.7Se0.3 are obtained by spark plasma sintering. All obtained samples are textured, the crystallographic axis of the texture (0 0 l) is directed parallel to the direction of the application of pressure during compaction. Development of the texture is confirmed by scanning electron microscopy and X-ray diffraction (XRD) analysis. The grains in the textured samples form an ordered lamellar structure, and the lamellar sheets lie in the plane perpendicular to the direction of pressing. An increase in the concentration of holmium leads to an increase in the degree of texturing. The thermoelectric properties of the bulk materials Bi2–xHoxTe2.7Se0.3 are also obtained

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基于碲化铋的掺钬纳米材料的合成、结构和热电特性
摘要 利用溶热合成法获得了粉末状热电材料 Bi2-xHoxTe2.7Se0.3(x = 0、0.001、0.0025、0.005、0.01 和 0.02)。这显示了获得基于掺杂钬的碲化铋纳米材料的可能性。研究了钬的浓度对合成颗粒的晶格参数、形态和平均尺寸的影响。通过火花等离子烧结法获得了块状材料 Bi2-xHoxTe2.7Se0.3。所有获得的样品都有纹理,纹理的晶体学轴线(0 0 l)平行于压制过程中施加压力的方向。扫描电子显微镜和 X 射线衍射(XRD)分析证实了纹理的形成。纹理样品中的晶粒形成了有序的薄片结构,薄片位于垂直于加压方向的平面上。钬浓度的增加会导致纹理程度的增加。还获得了块状材料 Bi2-xHoxTe2.7Se0.3 的热电性能
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
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0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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