Phase Formation of Novel Al-Mg-Zn-Cu-Si Lightweight High Entropy Alloy

Godson Nyaforkpa, Mohamed Emam, M. Gepreel
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Abstract

In this paper, a novel lightweight and low-cost Al35Mg20Zn15Cu10Si20 at. % (Al26.17Mg13.47Zn27.18Cu17.61Si15.57 wt.%) has been successfully designed, produced, and characterized. The thermophysical parameters were used to understand the phases associated with this alloy that show a low density of 3.42 g/cm3. The designed alloy was manufactured using both the arc and the muffle furnace. The alloy was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with an energy dispersive spectrometer (EDS). The alloy is characterized by a multiphase microstructure with three major phases including Mg2Si intermetallic phase and eutectic. The volume fraction of the eutectic and the intermetallic phases are 37.83 and 34.99 respectively. The heat capacities of the alloy were also determined by means of differential scanning calorimetry (DSC). The alloy provides a high latent heat of up to 124 J/g, which is one of the highest among the high-temperature metallic materials. The present work provides valuable information for researchers wishing to design and manufacture industrial-grade high-entropy alloys (HEAs).
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新型铝-镁-锌-铜-硅轻质高熵合金的相形成
本文成功设计、生产并表征了一种新型轻质低成本 Al35Mg20Zn15Cu10Si20 at.热物理参数用于了解这种合金的相关相,其密度较低,仅为 3.42 g/cm3。使用电弧炉和马弗炉制造了所设计的合金。使用 X 射线衍射(XRD)、配备能量色散光谱仪(EDS)的扫描电子显微镜(SEM)对合金进行了表征。合金的微观结构具有多相特征,主要有三相,包括 Mg2Si 金属间相和共晶。共晶相和金属间相的体积分数分别为 37.83 和 34.99。合金的热容量也是通过差示扫描量热法(DSC)测定的。该合金的潜热高达 124 J/g,是高温金属材料中潜热最高的材料之一。本研究为希望设计和制造工业级高熵合金(HEAs)的研究人员提供了有价值的信息。
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