Molecular-mass distribution of alkylphenolformaldehyde oligomers modified by imidazolines

M. N. Amiraslanova, N. Abdullayeva, R. V. Aliyeva, N. R. Bektashi, L. I. Aliyeva, R. A. Rustamov, Sh. R. Aliyeva, P. E. Isayeva
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Abstract

The molecular weight distribution of monoalkyl(C8–C12)phenolformaldehyde oligomers modified with imidazolines based on sunfl ower or corn oil fatty acids and polyamines – diethylenetriamine, triethylenetetraamine, polyethylene polyamines was determined by gel-chromatography. The influence of the component and quantitative composition on the parameters of the number average and weight average molecular weights, as well as on the polydispersity of oligomers, was studied. Regularities have been revealed and assumptions have been made regarding repeating monoalkyl (C8-C12)phenol-formaldehyde fragments in the composition of oligomeric macromolecules.
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咪唑类修饰的烷基酚甲醛低聚物的分子质量分布
通过凝胶色谱法测定了用基于太阳油或玉米油脂肪酸的咪唑啉和多胺(二乙烯三胺、三乙烯四胺、聚乙烯多胺)改性的单烷基(C8-C12)酚醛低聚物的分子量分布。研究了组分和定量组成对数均分子量和重均分子量参数以及低聚物多分散性的影响。研究揭示了低聚物大分子组成中重复单烷基(C8-C12)苯酚-甲醛片段的规律性,并提出了相关假设。
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