Danyang Cheng, Shixiang Yu, Meng Wang* and Ding Ma*,
{"title":"Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine","authors":"Danyang Cheng, Shixiang Yu, Meng Wang* and Ding Ma*, ","doi":"10.1021/prechem.3c00113","DOIUrl":null,"url":null,"abstract":"<p >A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and <i>N</i>,<i>N</i>′-dimethylethylenediamine to efficiently produce high-purity H<sub>2</sub>. In this process, the Cu/ZnO/Al<sub>2</sub>O<sub>3</sub> catalyst displayed superior activity in hydrogen production, with Cu<sup>+</sup> identified as the major active site through comprehensive characterization.</p>","PeriodicalId":29793,"journal":{"name":"Precision Chemistry","volume":"2 4","pages":"138–142"},"PeriodicalIF":0.0000,"publicationDate":"2024-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/prechem.3c00113","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Precision Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/prechem.3c00113","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and N,N′-dimethylethylenediamine to efficiently produce high-purity H2. In this process, the Cu/ZnO/Al2O3 catalyst displayed superior activity in hydrogen production, with Cu+ identified as the major active site through comprehensive characterization.
期刊介绍:
Chemical research focused on precision enables more controllable predictable and accurate outcomes which in turn drive innovation in measurement science sustainable materials information materials personalized medicines energy environmental science and countless other fields requiring chemical insights.Precision Chemistry provides a unique and highly focused publishing venue for fundamental applied and interdisciplinary research aiming to achieve precision calculation design synthesis manipulation measurement and manufacturing. It is committed to bringing together researchers from across the chemical sciences and the related scientific areas to showcase original research and critical reviews of exceptional quality significance and interest to the broad chemistry and scientific community.