Optical properties of pure and Sn-doped β-Ga2O3 single crystals grown by optical float zone technique

Abstract

High-quality single crystals of both pure and Sn:β-Ga₂O₃ single crystals were grown using the optical floating zone technique and a comprehensive study of its luminescence and scintillation properties was carried out. The pure and Sn:β-Ga₂O₃ grown crystals were oriented along (1 0 0) by Laue diffraction pattern and its monoclinic structure was confirmed using a single crystal XRD. X-ray induced luminescence spectrum shows a maximum emission peak at 365 nm. The cut off wavelength was observed around 258 nm and the optical band gap was calculated to be 4.64 eV from UV–Vis-NIR transmission spectroscopy. The room temperature Raman spectra were recorded and the various vibration modes were investigated. Low temperature (10 to 300 K) and high temperature (325 to 675 K) TL measurements were carried out on X-ray irradiated crystals and its TL kinetic parameters such as activation energy (eV) and frequency factor (S) were calculated. Scintillation decay time profiles were measured for both pure and Sn-doped crystals under ¹³⁷Cs γ-ray excitation. The calculated scintillation light output is 2300 Ph/5.5 Mev for Sn:β-Ga₂O₃ crystal under α-particle excitation from ²⁴¹Am radiation source.