Majid Safaei-Farouji , David Misch , Reinhard F. Sachsenhofer , Max Rauscher , Nikolaos Kostoglou
{"title":"From abandoned mines to carbon sinks: Assessing the CO2 storage capacity of Austrian low-rank coal deposits","authors":"Majid Safaei-Farouji , David Misch , Reinhard F. Sachsenhofer , Max Rauscher , Nikolaos Kostoglou","doi":"10.1016/j.coal.2024.104495","DOIUrl":null,"url":null,"abstract":"<div><p>This study represents the first assessment of CO<sub>2</sub> storage potential in Austrian coal seams. Coal samples were taken from Fohnsdorf and Leoben abandoned coal mines, with particular emphasis on the Fohnsdorf coal since Leoben coal reserves were largely mined during previous coal production. Several methods were used to compare coal characteristics, including Rock-Eval pyrolysis (RE), organic petrography, and low-pressure N<sub>2</sub> and CO<sub>2</sub> sorption measurements. Both Fohnsdorf and Leoben coal samples show low sulfur and ash yields, as well as correspondingly high total organic carbon (TOC) contents. The pyrolysis T<sub>max</sub> and vitrinite reflectance values agree with a low coal rank for both sites. According to the N<sub>2</sub> adsorption measurements at 77 K, low-lying mire coals from Fohnsdorf show a higher BET-specific surface area (BET-SSA) and BJH pore volume compared to raised-mire coals from Leoben. However, sapropelic shales and high-ash coals from Leoben show the highest BET-SSA and BJH pore volumes of all investigated samples and considerably exceed the N<sub>2</sub> adsorption volumes of pure coals from both locations (N<sub>2</sub> uptake up to 16 cm<sup>3</sup>/g; avg. for all samples 5.4 cm<sup>3</sup>/g). In contrast, the mean adsorbed CO<sub>2</sub> uptake measured at 273 K and ∼ 1 bar followed the order of Fohnsdorf low-lying mire coals > Leoben raised-mire coals > Leoben sapropelic coals and shales, ranging at ∼0.8 mmol/g, ∼0.7 mmol/g, and ∼ 0.2 mmol/g, respectively. This shows that BET-SSA and BJH equations did not allow for adequate estimation of CO<sub>2</sub> adsorption capacity trends in the investigated sample set. Furthermore, based on the existence of a hysteresis loop between CO<sub>2</sub> adsorption and desorption branches for all investigated samples, the occurrence of weak chemisorption phenomena during CO<sub>2</sub> adsorption is indicated. This effect helps to increase CO<sub>2</sub> uptake and storage safety since the chemisorption process is not fully reversible upon pressure decrease. Ultimately, the theoretical CO<sub>2</sub> sequestration potential of the remaining unmined Fohnsdorf coal reserves was estimated at 4.65 million tons, with an additional potential for enhanced coal bed methane production due to the gas-rich nature of Fohnsdorf coals with an estimated 1.2 billion m<sup>3</sup> of CH<sub>4</sub> in place.</p></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":null,"pages":null},"PeriodicalIF":5.6000,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0166516224000521/pdfft?md5=5c56313ec144f9edbe6b12d09c45dc7d&pid=1-s2.0-S0166516224000521-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Coal Geology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0166516224000521","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
This study represents the first assessment of CO2 storage potential in Austrian coal seams. Coal samples were taken from Fohnsdorf and Leoben abandoned coal mines, with particular emphasis on the Fohnsdorf coal since Leoben coal reserves were largely mined during previous coal production. Several methods were used to compare coal characteristics, including Rock-Eval pyrolysis (RE), organic petrography, and low-pressure N2 and CO2 sorption measurements. Both Fohnsdorf and Leoben coal samples show low sulfur and ash yields, as well as correspondingly high total organic carbon (TOC) contents. The pyrolysis Tmax and vitrinite reflectance values agree with a low coal rank for both sites. According to the N2 adsorption measurements at 77 K, low-lying mire coals from Fohnsdorf show a higher BET-specific surface area (BET-SSA) and BJH pore volume compared to raised-mire coals from Leoben. However, sapropelic shales and high-ash coals from Leoben show the highest BET-SSA and BJH pore volumes of all investigated samples and considerably exceed the N2 adsorption volumes of pure coals from both locations (N2 uptake up to 16 cm3/g; avg. for all samples 5.4 cm3/g). In contrast, the mean adsorbed CO2 uptake measured at 273 K and ∼ 1 bar followed the order of Fohnsdorf low-lying mire coals > Leoben raised-mire coals > Leoben sapropelic coals and shales, ranging at ∼0.8 mmol/g, ∼0.7 mmol/g, and ∼ 0.2 mmol/g, respectively. This shows that BET-SSA and BJH equations did not allow for adequate estimation of CO2 adsorption capacity trends in the investigated sample set. Furthermore, based on the existence of a hysteresis loop between CO2 adsorption and desorption branches for all investigated samples, the occurrence of weak chemisorption phenomena during CO2 adsorption is indicated. This effect helps to increase CO2 uptake and storage safety since the chemisorption process is not fully reversible upon pressure decrease. Ultimately, the theoretical CO2 sequestration potential of the remaining unmined Fohnsdorf coal reserves was estimated at 4.65 million tons, with an additional potential for enhanced coal bed methane production due to the gas-rich nature of Fohnsdorf coals with an estimated 1.2 billion m3 of CH4 in place.
期刊介绍:
The International Journal of Coal Geology deals with fundamental and applied aspects of the geology and petrology of coal, oil/gas source rocks and shale gas resources. The journal aims to advance the exploration, exploitation and utilization of these resources, and to stimulate environmental awareness as well as advancement of engineering for effective resource management.