Nanocomposites of Nanocarbon Functionalized Carbon Fibers—Manufacturing to Methodological Applications

Ayesha Kausar, Ishaq Ahmad
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Abstract

Carbon fibers have been technically applied in high performance materials and industrial scale applications. Importantly, carbon fiber reinforced composite materials have found applications in aerospace industries. These properties of carbon fiber reinforced composites depend upon the carbon fiber features such as length, orientation, surface properties, adhesion with matrices, etc. To improve the surface properties of carbon fibers and adhesion and interactions with polymers, fiber modification has been suggested as an efficient approach. Carbon nanoparticle or nanocarbon functionalized carbon fibers have been manufactured using various facile physical and chemical approaches such as electrospraying, electrophoretic deposition, chemical vapor deposition, etc. Consequently, the modified carbon fibers have nanocarbon nanoparticles such as graphene, carbon nanotube, nanodiamond, fullerene, and other nanocarbons deposited on the fiber surface. These nanocarbon nanoparticles have fine capability to improve interfacial linking of carbon fibers with the polymer matrices. The chemical vapor deposition has been adopted for uniform deposition of nanocarbon on carbon fibers and chemical methods involving physical or chemical modification have also been frequently used. The resulting advanced epoxy/carbon fiber/nanocarbon composites revealed improved tensile and physical profiles. This review basically aims manufacturing and technical aspects of polymer/fiber/nanofiller nanocomposites toward the development of high performance structures. The resulting morphology, strength, modulus, toughness, thermal stability, and other physical features of the nanocarbon functionalized carbon fibers have been enhanced. In addition, the fabricated polymer/fiber/nanofiller nanocomposites have fine interfacial adhesion, matrix-nanofiller-filler compatibility, and other characteristics. The application areas of these nanomaterials have been found wide ranging including the strengthened engineering structures, supercapacitors, shape memory materials, and several others.
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纳米碳功能化碳纤维纳米复合材料--从制造到方法应用
碳纤维已在技术上应用于高性能材料和工业领域。重要的是,碳纤维增强复合材料已在航空航天工业中得到应用。碳纤维增强复合材料的这些特性取决于碳纤维的特征,如长度、取向、表面特性、与基体的粘附性等。为了改善碳纤维的表面特性以及与聚合物的粘附性和相互作用,纤维改性被认为是一种有效的方法。碳纳米粒子或纳米碳功能化碳纤维的制造采用了各种简便的物理和化学方法,如电喷雾、电泳沉积、化学气相沉积等。因此,改性碳纤维表面沉积了石墨烯、碳纳米管、纳米金刚石、富勒烯等纳米碳纳米粒子。这些纳米碳纳米粒子具有改善碳纤维与聚合物基质界面连接的优良性能。在碳纤维上均匀沉积纳米碳时采用了化学气相沉积法,涉及物理或化学改性的化学方法也经常使用。由此产生的先进环氧树脂/碳纤维/纳米碳复合材料显示出更好的拉伸和物理特性。本综述主要针对聚合物/纤维/纳米填料纳米复合材料的制造和技术方面,旨在开发高性能结构。纳米碳功能化碳纤维的形态、强度、模量、韧性、热稳定性和其他物理特性都得到了改善。此外,制备的聚合物/纤维/纳米填料纳米复合材料具有良好的界面粘附性、基体-纳米填料-填料相容性和其他特性。这些纳米材料的应用领域非常广泛,包括强化工程结构、超级电容器、形状记忆材料等。
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