{"title":"The green reductive leaching of manganiferous iron ore and Mn3O4 nanoparticles production: Kinetic modeling and comparison of various reductants","authors":"Milad Karimi , Saeid Karimi , Ersin Yener Yazici","doi":"10.1016/j.jtice.2024.105479","DOIUrl":null,"url":null,"abstract":"<div><h3>Background</h3><p>Securing critical metals is crucial for the transition from fossil fuels to renewable energies. In this regard, extracting metals from various sources and low-grade ores can lead to the sustainable production of metals. Manganese, as a strategic metal, can play a significant role in achieving this goal.</p></div><div><h3>Methods</h3><p>In this study, various reductants such as oxalic acid, citric acid, ascorbic acid, acetic acid, tannic acid, hydrogen peroxide, iron (II) sulfate, sodium thiosulfate, and DL-malic acid were used to evaluate the feasibility and comparison on the manganiferous iron ore leaching.</p></div><div><h3>Significant findings</h3><p>DL-malic acid was chosen as the main reductant to investigate other factors because it is novel (as a reductant), eco-friendly, cost-effective, accessible, and easily storable. Therefore, more detailed studies on the dissolution of manganiferous iron ore in the presence of DL-malic acid as the reductant were carried out considering different levels of temperature, particle size, acid concentrations, and leaching time. Increasing the temperature from 298 K to 348 K notably boosted the leaching recovery from 27.00 % to 70.11 %. It was observed that decreasing the ore particle size from -212 μm to -38 μm resulted in an enhancement of leaching recovery from 57.74 % to 70.11 %. Also, adding only 250 % stoichiometry of DL-malic acid notably increased the leaching recovery to 70.11 %, compared to just 5.32 % in a reductant-free medium. It should be noted that the concentration of sulfuric acid had a direct impact on leaching recovery, increasing by 28.28 % with a concentration of 0.5 M and by 93.08 % with a concentration of 4 M. In this research work, the kinetic of the leaching process was modeled using the modified shrinking core model (MSCM). The calculated activation energy was about 33 kJ/mole, which confirmed that the mixed mechanism controlled the reaction. Mn<sub>3</sub>O<sub>4</sub> nanoparticles were synthesized using a pregnant leach solution (PLS) and through a multi-stage co-precipitation method. In this method, hydrogen peroxide was used to modify the manganese hydroxide phase as a more eco-friendly method than other heat treatment methods. The SEM and EDX analyses revealed an average particle size of 80 nm with spherical shapes and no impurities. The XRD pattern of the synthesized nanoparticles confirmed the Mn<sub>3</sub>O<sub>4</sub> phase composition.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":null,"pages":null},"PeriodicalIF":5.5000,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Taiwan Institute of Chemical Engineers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1876107024001378","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Background
Securing critical metals is crucial for the transition from fossil fuels to renewable energies. In this regard, extracting metals from various sources and low-grade ores can lead to the sustainable production of metals. Manganese, as a strategic metal, can play a significant role in achieving this goal.
Methods
In this study, various reductants such as oxalic acid, citric acid, ascorbic acid, acetic acid, tannic acid, hydrogen peroxide, iron (II) sulfate, sodium thiosulfate, and DL-malic acid were used to evaluate the feasibility and comparison on the manganiferous iron ore leaching.
Significant findings
DL-malic acid was chosen as the main reductant to investigate other factors because it is novel (as a reductant), eco-friendly, cost-effective, accessible, and easily storable. Therefore, more detailed studies on the dissolution of manganiferous iron ore in the presence of DL-malic acid as the reductant were carried out considering different levels of temperature, particle size, acid concentrations, and leaching time. Increasing the temperature from 298 K to 348 K notably boosted the leaching recovery from 27.00 % to 70.11 %. It was observed that decreasing the ore particle size from -212 μm to -38 μm resulted in an enhancement of leaching recovery from 57.74 % to 70.11 %. Also, adding only 250 % stoichiometry of DL-malic acid notably increased the leaching recovery to 70.11 %, compared to just 5.32 % in a reductant-free medium. It should be noted that the concentration of sulfuric acid had a direct impact on leaching recovery, increasing by 28.28 % with a concentration of 0.5 M and by 93.08 % with a concentration of 4 M. In this research work, the kinetic of the leaching process was modeled using the modified shrinking core model (MSCM). The calculated activation energy was about 33 kJ/mole, which confirmed that the mixed mechanism controlled the reaction. Mn3O4 nanoparticles were synthesized using a pregnant leach solution (PLS) and through a multi-stage co-precipitation method. In this method, hydrogen peroxide was used to modify the manganese hydroxide phase as a more eco-friendly method than other heat treatment methods. The SEM and EDX analyses revealed an average particle size of 80 nm with spherical shapes and no impurities. The XRD pattern of the synthesized nanoparticles confirmed the Mn3O4 phase composition.
期刊介绍:
Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.