Enhanced Hydrophobic Double-Layer Nanofibers Membranes for Direct Contact Membrane Distillation

Nawras N. Safi, Basma I. Waisi
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Abstract

There are several uses for electrospun nanofiber membranes because of their unique properties. Electrospinning, under suitable conditions, has allowed for the successful fabrication of nanofibrous membranes. This research, a dual-layer membrane was prepared and applied in a direct contact membrane distillation (DCMD) system. Polyac-rylonitrile (PAN) based electrospun nanofibers comprised the initial (base) layer. Hydrophobic electrospun nanofi - bers made from polymethyl methacrylate (PMMA) comprised the second (top) layer. The analysis was carried out using contact angle measurements and scanning electron microscopy (SEM) for the morphology and wetting of a series of two-layer nanofiber membranes that were made with different percentages of PAN: PMMA. The study examined how the permeate flux was affected by changes in feed concentration, feed temperature, and feed flow rate. and optimized within a logical framework. These included feed inlet temperatures between 35 and 55 °C, salt concentrations between 70,000 and 210,000 ppm, and rates of supply flow of 0.2, 0.4, and 0.6 L/min. DCMD find - ings for the (25 PAN:75PMMA) membrane displayed that the amount of salt it rejected was better than 99.356% with flux 51.872 kg/m 2 .h and a penetrate through conductivity lower down 334 µs/cm when performed under optimally supplied conditions (i.e., 70 g/L; 0.6 L/min; and 55 °C).
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用于直接接触膜蒸馏的增强型疏水双层纳米纤维膜
电纺纳米纤维膜因其独特的性能而有多种用途。在适当的条件下,电纺丝可以成功制造纳米纤维膜。本研究制备了一种双层膜,并将其应用于直接接触膜蒸馏(DCMD)系统。基于聚丙烯腈(PAN)的电纺纳米纤维构成了初始(基础)层。第二层(顶层)是由聚甲基丙烯酸甲酯(PMMA)制成的疏水性电纺纳米纤维。使用接触角测量法和扫描电子显微镜 (SEM) 分析了一系列双层纳米纤维膜的形态和润湿情况,这些纳米纤维膜由不同比例的 PAN:PMMA 制成。该研究考察了渗透通量如何受到进料浓度、进料温度和进料流速变化的影响。其中包括进料温度介于 35 至 55 °C,盐浓度介于 70,000 至 210,000 ppm,以及 0.2、0.4 和 0.6 升/分钟的供料流速。DCMD 对 (25 PAN:75PMMA) 膜的研究结果表明,在最佳供应条件下(即 70 克/升;0.6 升/分钟;55 °C),其盐剔除量优于 99.356%,通量为 51.872 公斤/米 2 .小时,穿透电导率低于 334 微秒/厘米。
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