Fractal Properties of Composite-Modified Carbon Paste Electrodes—A Comparison between SEM and CV Fractal Analysis

G. Dobrescu, Ramona Georgescu-State, F. Papa, Jacobus (Koos) Frederick van Staden, R. State
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Abstract

The fractal properties of carbon paste electrodes (CPEs) and carbon paste electrodes modified with ionic liquid (IL), AuTiO2/graphene oxide, and IL/AuTiO2/graphene oxide were investigated using scanning electron microscopy (SEM), and cyclic voltammetry (CV). The impact of fractal dimensions and self-similarity ranges on electrochemical responses was underlined. It was proved that a higher fractal dimension and a broad self-similarity domain lead to a higher electrochemical response. Results indicated that IL/AuTiO2/graphene oxide composite-modified CPEs are a great candidate to be used as electrochemical sensors, with a high fractal dimension and large self-similarity domain.
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复合材料改性碳浆电极的分形特性--SEM 与 CV 分形分析的比较
利用扫描电子显微镜(SEM)和循环伏安法(CV)研究了碳糊电极(CPEs)和用离子液体(IL)、氧化金钛/氧化石墨烯、IL/氧化金钛/氧化石墨烯修饰的碳糊电极的分形特性。研究强调了分形尺寸和自相似性范围对电化学反应的影响。事实证明,分形维数越高,自相似度域越宽,电化学响应越高。结果表明,IL/AuTiO2/氧化石墨烯复合改性 CPE 具有较高的分形维度和较大的自相似域,是用作电化学传感器的理想候选材料。
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