Phenol Adsorption from Simulated Wastewater Using Activated Spent Tea Leaves

Noora A. Raheem, Najwa S. Majeed, Zahraa Al Timimi
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Abstract

The removal of phenol from wastewater has become a significant environmental concern because of its toxicity, even at low concentrations. This research focuses on the removal of phenol using spent tea leaves (STLs) as an adsorbent. SEM and FTIR tests were used to evaluate the surface characterization of the STLs. The effect of the parameters such as initial phenol concentration (20 - 80 mg. L-1), pH (3 - 12), temperature (25 - 55 °C), contact period (30-330 min), and dose (0.25 - 2.5) on the removal of phenol was studied. The highest removal of phenol of 82% was obtained at 20 mg. L-1 of initial phenol concentration, 4 h of the contact period, pH of 3, adsorbent dose of 2 g, and temperature of 55 °C. The results of the kinetic study fitted the pseudo-second-order model. The obtained data for phenol adsorption isotherm fitted to the Langmuir, Freundlich, and Temkin models. The Temkin isotherm model presented the best fitting with phenol adsorption isotherm experimental data based on the correlation coefficients. According to the findings, the STLs can effectively remove phenol from wastewater.
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利用活性废茶叶吸附模拟废水中的苯酚
由于苯酚即使在低浓度下也具有毒性,因此从废水中去除苯酚已成为一个重要的环境问题。本研究的重点是利用废茶叶(STL)作为吸附剂去除苯酚。SEM 和 FTIR 测试用于评估 STL 的表面特征。研究了初始苯酚浓度(20 - 80 mg. L-1)、pH 值(3 - 12)、温度(25 - 55 °C)、接触时间(30-330 分钟)和剂量(0.25 - 2.5)等参数对苯酚去除率的影响。当初始苯酚浓度为 20 mg.L-1、接触时间 4 h、pH 值 3、吸附剂剂量 2 g 和温度 55 °C 时,苯酚的去除率最高,达到 82%。动力学研究结果符合假二阶模型。所获得的苯酚吸附等温线数据符合 Langmuir、Freundlich 和 Temkin 模型。根据相关系数,Temkin 等温线模型与苯酚吸附等温线实验数据的拟合效果最好。研究结果表明,STL 能有效去除废水中的苯酚。
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26
审稿时长
12 weeks
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