Effect of Silicide and α2 Phase on the Creep Behavior of TC25G Alloy at High Temperature

IF 3.3 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Metals and Materials International Pub Date : 2024-03-29 DOI:10.1007/s12540-024-01641-9
Zhuomeng Liu, Shewei Xin, Yongqing Zhao, Bohao Dang
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Abstract

TC25G alloy was heat treated at 950 °C/3 h, AC + 580 °C/6 h, AC and the bimodal structure with primary α phase + β transition structure was obtained. The creep properties of the alloy were tested in 550–600 °C/150–250 MPa. The results show that the precipitations of silicide and α2 phase is accompanied by the creep process. α2 phase plays a dispersion strengthening role in both the primary and steady-state creep stages. However, in the accelerated creep stage, the mechanism of α2 phase and dislocation changes from cutting mechanism to bypassing mechanism, and the strengthening effect is weakened. Silicide inhibits grain boundary slip mainly in the primary creep stage, and inhibits dislocation slip in the steady-state and accelerated creep stages. At 550 °C, n = 1.6 and Q = 280–371 kJ/mol (150–250 MPa) indicate that the creep of the alloy is a self-diffusion process, and the creep deformation is mainly controlled by dislocation slip. At 570–600 °C, n = 3.2 indicates that the dislocation climb controls the creep deformation. Meanwhile, compared with Q = 274 kJ/mol at low stress (150 MPa), Q = 365 kJ/mol at the high stress (200–250 MPa) indicates that the second phase precipitation enhancement is enhanced.

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硅化物和 α2 相对 TC25G 合金高温蠕变行为的影响
TC25G 合金在 950 °C/3 h, AC + 580 °C/6 h, AC 下进行热处理,获得了主α相 + β过渡结构的双峰结构。在 550-600 °C/150-250 MPa 下测试了合金的蠕变性能。结果表明,硅化物和 α2 相的析出伴随着蠕变过程。在初级蠕变和稳态蠕变阶段,α2 相都起到了分散强化的作用。然而,在加速蠕变阶段,α2 相和位错的作用机理由切割机理变为绕射机理,强化作用减弱。硅化物主要在初级蠕变阶段抑制晶界滑移,在稳态和加速蠕变阶段抑制位错滑移。在 550 °C 时,n = 1.6 和 Q = 280-371 kJ/mol (150-250 MPa)表明合金的蠕变是一个自扩散过程,蠕变变形主要由位错滑移控制。在 570-600 °C 时,n = 3.2 表明位错攀升控制着蠕变变形。同时,与低应力(150 兆帕)时的 Q = 274 kJ/mol 相比,高应力(200-250 兆帕)时的 Q = 365 kJ/mol 表明第二相析出增强。
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来源期刊
Metals and Materials International
Metals and Materials International 工程技术-材料科学:综合
CiteScore
7.10
自引率
8.60%
发文量
197
审稿时长
3.7 months
期刊介绍: Metals and Materials International publishes original papers and occasional critical reviews on all aspects of research and technology in materials engineering: physical metallurgy, materials science, and processing of metals and other materials. Emphasis is placed on those aspects of the science of materials that are concerned with the relationships among the processing, structure and properties (mechanical, chemical, electrical, electrochemical, magnetic and optical) of materials. Aspects of processing include the melting, casting, and fabrication with the thermodynamics, kinetics and modeling.
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