Corrosion Resistance of Scraped Copper in Velocity Varied Inland Water of Bangladesh

M Muzibur Rahman, Raisha Hasan Chowdhury, Tahian Ahmed Rafi, S Reaz Ahmed
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Abstract

Copper (Cu) is widely used for electrical wires, equipment parts, and components in commercial, industrial, and marine fields due to its excellent electromechanical properties. With rapid scientific and technological advancement and economic development, the demand for copper is increasing continuously. As such, scraped items have become important to meet the rising demand considering the depletion level of copper ores in nature. But sometimes old copper contains tin (Sn), lead (Pb), etc., which may alter its properties. Thus, it is necessary to characterize different properties, including corrosion resistance, to explore the appropriate engineering applications of scraped copper waste items. In this context, the present research reports the study of the corrosion behavior of pure Cu and scraped Cu in the river water environment of Bangladesh for the submersed period of 36 days. The investigations have been carried out for three relative velocity conditions of fluid, i.e., 0, 2 and 4 m/s. A gravimetric analysis was done to find out the corrosion rate. The results of this study indicate that the presence of only 1%Sn and 1%Pb in copper has significantly increased the corrosion rate in all three velocity conditions. At the same time, scraped copper's average corrosion rate has been increased by about 10% while the relative velocity is changed from 0 to 4 m/s. Micrographs have confirmed the extent of corrosion severity resulting from chemical composition and fluid velocity alterations.
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孟加拉国不同流速内河中刮削铜的抗腐蚀性能
铜(Cu)因其优异的机电性能,被广泛用于商业、工业和航海领域的电线、设备部件和组件。随着科技进步和经济发展,铜的需求量不断增加。因此,考虑到自然界中铜矿的枯竭程度,废旧物品已成为满足日益增长的需求的重要手段。但有时旧铜中含有锡(Sn)、铅(Pb)等物质,这些物质可能会改变铜的特性。因此,有必要对包括耐腐蚀性在内的不同特性进行表征,以探索废铜的适当工程应用。在此背景下,本研究报告研究了纯铜和废铜在孟加拉国河水环境中 36 天的浸没期的腐蚀行为。研究在三种相对流速条件下进行,即 0、2 和 4 米/秒。为了解腐蚀率,进行了重量分析。研究结果表明,在所有三种速度条件下,铜中仅含有 1%Sn 和 1%Pb 会显著增加腐蚀率。同时,当相对速度从 0 米/秒变为 4 米/秒时,刮削铜的平均腐蚀速率增加了约 10%。显微照片证实了化学成分和流体速度变化导致的腐蚀严重程度。
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