Study the Structure Properties of CdTe and CdTe/CdSe Quantum Dots at pH=12 using an Aqueous Method

Q4 Earth and Planetary Sciences Iraqi Journal of Science Pub Date : 2024-02-29 DOI:10.24996/ijs.2024.65.2.13
H. Noori, A. F. Abdulameer
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Abstract

     This research aims to study the structural properties of cadmium telluride (CdTe) core QDs and cadmium telluride/ cadmium selenium (CdTe/CdSe) core-shell QDs at pH 12. The QDs were prepared using aqueous synthesis by reflux process. The structural properties of the QDs were studied using X-ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray spectroscopy (EDX), and Transmission Electron Microscopy (TEM). The results of the XRD analysis for CdTe QDs and CdTe/CdSe QDs showed that they have three diffraction peaks in the directions (111), (220), and (331) with a slight shift in the diffraction peaks of CdTe/CdSe QDs, which indicates the successful packing of selenium atoms around CdTe. FESEM results confirmed that CdTe and CdTe/CdSe QDs possess quantum spherical NPs with diameters ranging from 27 nm to 41 nm. The EDX results confirm corrections of added concentrations The histogram images of the TEM analysis show that the diameters of CdTe and CdTe/CdSe are 7nm and 9 nm, respectively.
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用水溶液法研究碲化镉和碲化镉/硒化镉量子点在 pH=12 时的结构特性
本研究旨在研究 pH 值为 12 的碲化镉(CdTe)核壳 QDs 和碲化镉/硒(CdTe/CdSe)核壳 QDs 的结构特性。使用 X 射线衍射 (XRD)、场发射扫描电子显微镜 (FESEM)、能量色散 X 射线光谱 (EDX) 和透射电子显微镜 (TEM) 研究了 QDs 的结构特性。CdTe QDs 和 CdTe/CdSe QDs 的 XRD 分析结果显示,它们在 (111)、(220) 和 (331) 方向上有三个衍射峰,CdTe/CdSe QDs 的衍射峰略有偏移,这表明硒原子成功地堆积在 CdTe 周围。FESEM 结果证实,CdTe 和 CdTe/CdSe QDs 具有直径介于 27 纳米到 41 纳米之间的量子球形 NP。TEM 分析的直方图图像显示,CdTe 和 CdTe/CdSe 的直径分别为 7 纳米和 9 纳米。
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来源期刊
Iraqi Journal of Science
Iraqi Journal of Science Chemistry-Chemistry (all)
CiteScore
1.50
自引率
0.00%
发文量
241
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