Complexes of 2-hydroxynaphthylidene-2-aminothiazole with Titanium (III) and Vanadium (III)

Daya Veer, Mahe Safia, Mukesh Baboo, Reshu Johari
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Abstract

The synthesis and characterization of a new series of metal complexes of Titanium (III) and Vanadium (III) as a metal ion and 2-hydroxynaphthylidene-2-aminothiazole as a ligand are studied. The complexes [C14H15N2SO4.TiCl2] and [C14H13N2SO3.VCl2] have been characterized by elemental, infrared, electronic, absorption spectral, and magnetic susceptibility measurements. An octahedral geometry is predicted for Ti(III) and V(III) complexes.
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2-hydroxynaphthylidene-2-aminothiazole 与钛(III)和钒(III)的络合物
研究了以钛 (III) 和钒 (III) 为金属离子、以 2-hydroxynaphthylidene-2-aminothiazole 为配体的一系列新金属配合物的合成和表征。通过元素、红外、电子、吸收光谱和磁感应强度测量,对[C14H15N2SO4.TiCl2]和[C14H13N2SO3.VCl2]配合物进行了表征。预测 Ti(III) 和 V(III) 复合物具有八面体几何结构。
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