Oscillations through a barrier tunneling potential for a particle in a central potential (double potential well)

H. Erbil, A. S. Selvi
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Abstract

In some molecules such as ammonia, double vibrations are observed at small energies. These small vibrations are thought to arise from double well potentials. To explain these small energy gaps, double potential wells are investigated, and complex calculations are made. Until recently, since the exact solution of the Schrödinger equation was not known, approximate solutions were always obtained. The exact solution of the Schrödinger equation is now known. In previous studies, a simple procedure for the general solution of the radial Schrödinger Equation has been found for spherical symmetric potentials without making any approximation. In this article, the Schrodinger equation was solved with this new solution method. It has been applied to the oscillations through a barrier tunneling potential for a particle in a central quadratic deformed potential well (double potential well). It is seen that there is no need to look for complex potentials to explain the double wells observed in small vibrations in ammonia and similar molecules, they were compared with experimentally measured energies. The results were found to be fully compatible. It has been seen that there can always be double well potentials at small energies for all molecules, atomic nuclei, and similar particles with angular momentum other than zero.
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中心势(双势井)中粒子通过势垒隧道势的振荡
在一些分子(如氨)中,可以观察到小能量的双振动。这些小振动被认为是由双势阱引起的。为了解释这些小能量间隙,对双势阱进行了研究,并进行了复杂的计算。直到最近,由于薛定谔方程的精确解还不为人所知,人们一直在寻找近似解。现在,薛定谔方程的精确解已为人所知。在以往的研究中,人们已经找到了一种简单的径向薛定谔方程的一般解法,这种解法适用于球面对称势,不需要做任何近似处理。本文采用这一新的求解方法求解薛定谔方程。它被应用于粒子在中心二次变形势阱(双势阱)中通过势垒隧道势的振荡。结果表明,无需寻找复杂的势阱来解释在氨和类似分子的微小振动中观察到的双势阱。结果发现两者完全吻合。由此可见,对于角动量不为零的所有分子、原子核和类似粒子,在小能量时总是存在双井电势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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