Thermodynamics of interaction of inulin complex with water

Yu. A. Maksimenko, O. Konnova, I. Y. Aleksanian
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Abstract

Currently, the key trends in the global food market include the rapidly developing functional nutrition industry, which is of great interest to consumers. Inulin is a natural polysaccharide of plant origin, consisting of residues of E-fructofuranose (fructose). The object of the research is inulin extract from Jerusalem artichoke at different humidity levels. It has been established that to intensify the drying process of inulin extract, it is advisable to increase the mass transfer surface, which can be achieved by spraying the initial product, and using volumetric energy supply methods, in particular, radiation energy supply. The important and most energy-intensive stages of drying are carried out in the hygroscopic area of equilibrium humidity of the object of the research, which determines the intensity and mechanism of the dehumidification operation in order to increase the degree of perfection, select rational operating parameters, adapt to the object of the analysis and solve a mathematical model of removal moisture from it. Based on the sorption isotherms and hygroscopic parameters of the inulin extract obtained in preliminary studies, obtained by dehydrating the inulin extract from Jerusalem artichoke (variety «Skorospelka», grown by JSC «Chaganskoe», the bAstrakhan region), a thermodynamic analysis of the process of sorption and desorption was carried out in different ranges of humidity variation. The total binding energy of moisture with the dry residue of inulin and its thermodynamic components were found. The data obtained do not contradict known literature sources and can be recommended when designing processes for removing moisture from inulin extract and designing drying devices.
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菊粉复合物与水相互作用的热力学
目前,全球食品市场的主要趋势包括快速发展的功能性营养产业,这也引起了消费者的极大兴趣。菊粉是一种源自植物的天然多糖,由 E-呋喃果糖(果糖)残留物组成。研究对象是从不同湿度下的菊芋中提取菊粉。已经证实,要强化菊粉提取物的干燥过程,最好是增加传质面,这可以通过喷洒初始产品和使用容积供能方法(特别是辐射供能)来实现。干燥过程中最重要、最耗能的阶段是在研究对象平衡湿度的吸湿区进行的,这就决定了除湿操作的强度和机理,以便提高完善程度,选择合理的操作参数,适应分析对象,并求解从中去除水分的数学模型。通过对耶路撒冷朝鲜蓟(品种为 "Skorospelka",由俄阿斯特拉罕州 "Chaganskoe "股份公司种植)中的菊淀提取物进行脱水处理,在初步研究中获得了菊淀提取物的吸附等温线和吸湿参数,在此基础上对不同湿度变化范围内的吸附和解吸过程进行了热力学分析。研究发现了水分与菊粉干残渣的总结合能及其热力学成分。所获得的数据与已知的文献资料并不矛盾,可作为设计菊粉提取物除湿工艺和设计干燥设备的参考。
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