DEVELOPMENT OF ECOFRIENDLY PLASTIC BAGS FROM BIOTHERMOPLASTIC COMPOSITE OF MODIFIED CASSAVA STARCH–GLUCOMANNAN-POLYVINYL ALCOHOL-POLYCAPROLACTONE

B. A. Harsojuwono, Wayan Arnata, A. Hartiati, Ida Bagus, Wayan Gunam, Y. Setiyo
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Abstract

The purpose of the study was to determine the type of molding material and the sealing temperature in the formation of ecofriendly plastic bags made from a Modified Starch – Glucomannan – Polyvinyl Alcohol – Polycaprolactone (MSGPVAPCL) biothermoplastic composites. The study used a factorial randomized block design experiment. Factor 1: the type of molding material consists of Teflon and acrylic while factoring 2: the sealing temperature with levels of 90, 95, 100, 105, and 110 °C. Mechanical, physical, biological and chemical characteristics were observed. The research results show that the type of teflon molding material and the sealing temperature of 105°C gave the best characteristics of ecofriendly plastic bags with a tensile strength value of 28.62 MPa, elongation at break of 8.68%, Young's modulus 449.44 MPa, a heat seal tensile strength on the bag handle of 6.10 N, a heat seal tensile strength on the bag bottom of  4.10 N, tear strength direction longitudinally of 3.61 N, transverse tear strength of 1.78 N, WVTR of 91.23 g/m2/day, swelling of 5.31% and biodegradation time of 7.00 days, the maximum evaporation temperature of 72.43 °C, degradation temperature of 220.97 °C and a weight loss of 30.07%, a crystalline degree of 20.71% and an amorphous degree of 79.29%, a smooth longitudinal surface profile with slight waves and a transverse surface profile showing the presence of waves and fine fibers, containing functional groups O-H alcohol, C=O, C=C, C-O and (CH2)n and no heavy metals were detected. 
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利用改性木薯淀粉-葡甘露聚糖-聚乙烯醇-聚己内酯的生物热塑性复合材料开发环保塑料袋
本研究的目的是确定成型材料的类型以及用改性淀粉-葡甘露聚糖-聚乙烯醇-聚己内酯(MSGPVAPCL)生物热塑性复合材料制成的生态友好型塑料袋的密封温度。研究采用了因子随机区组设计实验。因子 1:成型材料的类型包括聚四氟乙烯和丙烯酸;因子 2:密封温度,分别为 90、95、100、105 和 110 ℃。研究观察了机械、物理、生物和化学特性。研究结果表明,聚四氟乙烯成型材料类型和 105°C 的密封温度使生态环保塑料袋具有最佳特性,其拉伸强度值为 28.62 兆帕,断裂伸长率为 8.68%,杨氏模量为 449.44 兆帕,袋柄的热封拉伸强度为 6.10 牛顿,袋底的热封拉伸强度为 4.10 牛顿,纵向撕裂强度为 3.61 牛顿,横向撕裂强度为 1.78 牛顿,WVTR 为 91.23 克/平方米/天,膨胀率为 5.31%,生物降解时间为 7.00 天,最高蒸发温度为 72.43 °C,降解温度为 220.97 °C,失重率为 30.07%,结晶度为 20.71%,无定形度为 79.29% ,纵向表面光滑,有轻微波纹,横向表面有波纹和细小纤维,含有官能团 O-H 醇、C=O、C=C、C-O 和 (CH2)n,未检测到重金属。
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