Opal Cement in the Eocene Castle Rock Conglomerate, Central Colorado

M. Longman, Nik Svihlik, Joan Burleson, J. Hagadorn
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Abstract

The Castle Rock Conglomerate is one of Colorado’s most iconic, youngest, and coarsest grained rock units. It is also one of the hardest sedimentary rocks in Colorado and forms prominent buttes in the southwestern Denver Basin. Yet the reasons for its induration and resistance to weathering have not previously been investigated. Sedimentologic observations paired with sedimentary petrology indicate that much of the unit is comprised of a planar-bedded to cross-bedded, mostly poorly sorted, angular to subrounded assemblage of quartz, K-feldspar, quartzite, and unusually large volcanic rock fragments along with some plagioclase and mica flakes. The largest volcanic rock fragments are up to ∼2 m in size and composed of the immediately subjacent Wall Mountain Tuff of late Eocene age. Sedimentary rock fragments and well-rounded quartz grains are rare. Together these features suggest a diverse and relatively proximal provenance for the unit. Pervasive opaline cement coats most grains, and locally exhibits pendant features typical of vadose precipitation. These opal cements formed prior to any grain compaction and indicate early silica precipitation at shallow burial depths. Where the primary pores were not completely cemented by the opal, most were later filled with length-fast chalcedony cement. We hypothesize that cementation of the conglomerate began soon after deposition as weathering of the Wall Mountain Tuff and weathering of clasts of the tuff within the conglomerate, yielded ground water super-saturated with silica. These fluids initially catalyzed precipitation of common opal (hydrous amorphous silica) and later fostered precipitation of length-fast chalcedony. Together, these cements created a silica-cemented “concrete” much more resistant to weathering than any carbonate-cemented sandstone, and much harder than man-made calcite-cemented concrete found in many sidewalks and roadways.
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科罗拉多州中部始新世城堡岩砾岩中的蛋白石胶结物
城堡岩砾岩是科罗拉多州最具代表性、最年轻、颗粒最粗的岩石单元之一。它也是科罗拉多州最坚硬的沉积岩之一,并在丹佛盆地西南部形成了突出的火山口。然而,人们以前并没有研究过其硬化和抗风化的原因。沉积学观察结果和沉积岩石学表明,该单元大部分由平面层理至交叉层理组成,大部分分选较差,由石英、钾长石、石英岩、异常大的火山岩碎片以及一些斜长石和云母片组成的角状至近圆形集合体。最大的火山岩碎片大小可达 2 米,由紧邻的晚始新世时期的华尔山凝灰岩组成。沉积岩碎片和圆形石英颗粒则很少见。这些特征共同表明了该单元的多样性和相对较近的来源。普遍存在的乳白胶结物包裹着大部分颗粒,局部呈现出典型的浸润沉淀的下垂特征。这些乳白胶结物在任何颗粒压实之前就已形成,表明埋藏深度较浅的早期硅沉淀。在原生孔隙未完全被蛋白石胶结的地方,大部分孔隙后来都被长度较快的玉髓胶结物填充。我们推测,砾岩的胶结始于沉积后不久,因为华尔山凝灰岩的风化以及砾岩中凝灰岩碎屑的风化,产生了含硅过饱和的地下水。这些流体最初催化了普通蛋白石(水合无定形二氧化硅)的沉淀,后来又促进了长快玉髓的沉淀。这些胶结物共同形成了硅质胶结的 "混凝土",比任何碳酸盐胶结的砂岩都更耐风化,也比许多人行道和公路上的人造方解石胶结混凝土更坚硬。
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