Thermodynamic and kinetic understanding for managing the controllability of interfacial polymerization

IF 26 1区 化学 Q1 POLYMER SCIENCE Progress in Polymer Science Pub Date : 2024-04-02 DOI:10.1016/j.progpolymsci.2024.101815
Chang Liu , Cheng-Ye Zhu , Chao Zhang , Hao-Cheng Yang , Zhi-Kang Xu
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Abstract

Interfacial polymerization serves as a revolutionary technique to create polymer membranes such as polyamides, polyesters, and covalent organic frameworks, holding exceptional promise in numerous scenarios from liquid and gas separation to energy conversion and harvesting. Despite significant achievements, the fundamental principles of interfacial polymerization have been rarely discussed systemically, particularly from the perspective of thermodynamics, kinetics, and their combinations. This knowledge gap results in the lack of rational design and tailoring of interfacial polymerization. This review aims to revisit interfacial polymerization, integrating thermodynamics and kinetics to bridge the remained knowledge gap. We dissect the process into distinct physicochemical stages, including monomer dissolution, molecular diffusion, chemical reactions, and phase separation. Each stage is examined using thermodynamic and kinetic theories, underlining recent strides in refining process control. Furthermore, the review confronts the unresolved theoretical aspects of interfacial polymerization and the challenges inherent in mastering its controllability. We conclude by offering insights into how a controlled approach to interfacial polymerization could substantially transform the landscape of state-of-the-art polymer membranes.

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通过热力学和动力学理解来管理界面聚合的可控性
界面聚合是一种革命性技术,可用于制造聚酰胺、聚酯和共价有机框架等聚合物膜,在液体和气体分离、能源转换和收集等众多应用领域大有可为。尽管取得了重大成就,但人们很少系统地讨论界面聚合的基本原理,特别是从热力学、动力学及其组合的角度。这一知识空白导致界面聚合缺乏合理的设计和定制。本综述旨在重新审视界面聚合,将热力学和动力学结合起来,弥合仍然存在的知识差距。我们将这一过程剖析为不同的物理化学阶段,包括单体溶解、分子扩散、化学反应和相分离。我们利用热力学和动力学理论对每个阶段进行了研究,强调了在完善过程控制方面取得的最新进展。此外,综述还探讨了界面聚合尚未解决的理论问题,以及掌握其可控性所面临的挑战。最后,我们深入探讨了界面聚合的可控方法如何能大幅改变最先进的聚合物膜的面貌。
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来源期刊
Progress in Polymer Science
Progress in Polymer Science 化学-高分子科学
CiteScore
48.70
自引率
1.10%
发文量
54
审稿时长
38 days
期刊介绍: Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.
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