Jiong GUO , Jinhai ANG , Yilin SHI , Ning ZHAO , Fukui XIAO , Xindong JIANG
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引用次数: 0
Abstract
Calcium cerium-based catalysts with different Ca:Ce molar ratio prepared by sol-gel method were characterized by XRD, N2 adsorption-desorption, FT-IR, XPS and CO2-TPD, and evaluated the activity for dimethyl carbonate (DMC) synthesis from propylene carbonate (PC) and methanol. The results indicated that more surface oxygen vacancies and more moderate basic sites are beneficial for methanol activation and thus leading to better catalytic activity. The PC conversion was 91.1% with DMC selectivity of 91.7% over 0.9CaCe under the reaction conditions-reaction time of 2 h, reaction temperature of 40 °C, methanol to propylene carbonate molar ratio of 15:1 and catalyst amount of 4% relative to the amount of PC.
期刊介绍：
Journal of Fuel Chemistry and Technology (Ranliao Huaxue Xuebao) is a Chinese Academy of Sciences(CAS) journal started in 1956, sponsored by the Chinese Chemical Society and the Institute of Coal Chemistry, Chinese Academy of Sciences(CAS). The journal is published bimonthly by Science Press in China and widely distributed in about 20 countries. Journal of Fuel Chemistry and Technology publishes reports of both basic and applied research in the chemistry and chemical engineering of many energy sources, including that involved in the nature, processing and utilization of coal, petroleum, oil shale, natural gas, biomass and synfuels, as well as related subjects of increasing interest such as C1 chemistry, pollutions control and new catalytic materials. Types of publications include original research articles, short communications, research notes and reviews. Both domestic and international contributors are welcome. Manuscripts written in Chinese or English will be accepted. Additional English titles, abstracts and key words should be included in Chinese manuscripts. All manuscripts are subject to critical review by the editorial committee, which is composed of about 10 foreign and 50 Chinese experts in fuel science. Journal of Fuel Chemistry and Technology has been a source of primary research work in fuel chemistry as a Chinese core scientific periodical.
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