Polymer-adjusted zinc anode towards high-performance aqueous zinc ion batteries

IF 26 1区 化学 Q1 POLYMER SCIENCE Progress in Polymer Science Pub Date : 2024-04-04 DOI:10.1016/j.progpolymsci.2024.101817
Zeping Liu , Bing Sun , Yu Zhang , Qixian Zhang , Lishuang Fan
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Abstract

High-safety and low-cost aqueous zinc ion batteries (AZIB) are expected to be used in large-scale energy storage systems. However, currently used zinc (Zn) anode materials are susceptible to derogatory processes such as dendrite growth or cause side reactions which limits their practical applications. Although polymeric materials have been specifically applied for Zn anode protection, the complicated composition and lack of understanding of the working mechanisms of currently used materials are not conducive to guiding further research. This review provides a summary and discussion of polymer materials that are used in AZIB applications and a platform for future material development. The importance of polymer materials and the advantages of their applications in Zn batteries are described. Subsequently, the latest progress in the design and optimization of polymer for stable Zn anodes is summarized from multiple perspectives, including electrolyte additives, artificial protective layers, hydrogel electrolytes, and novel separators. Finally, the future challenges and research directions of polymer-stabilized Zn anode are proposed.

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面向高性能锌离子水电池的聚合物调整锌阳极
高安全性、低成本的锌离子水电池(AZIB)有望用于大规模储能系统。然而,目前使用的锌(Zn)阳极材料容易出现枝晶生长等衰减过程或引起副反应,从而限制了其实际应用。虽然聚合物材料已被专门用于锌阳极保护,但其复杂的成分和对目前使用材料工作机制的不了解不利于指导进一步的研究。本综述对用于 AZIB 应用的聚合物材料进行了总结和讨论,并为未来的材料开发提供了一个平台。文中阐述了聚合物材料的重要性及其在锌电池中应用的优势。随后,从电解质添加剂、人工保护层、水凝胶电解质和新型隔膜等多个角度总结了用于稳定锌阳极的聚合物设计和优化的最新进展。最后,提出了聚合物稳定锌阳极的未来挑战和研究方向。
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来源期刊
Progress in Polymer Science
Progress in Polymer Science 化学-高分子科学
CiteScore
48.70
自引率
1.10%
发文量
54
审稿时长
38 days
期刊介绍: Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.
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