Fine quantitative characterization of high-H2S gas reservoirs under the influence of liquid sulfur deposition and adsorption

Abstract

In order to clarify the influence of liquid sulfur deposition and adsorption to high-H₂S gas reservoirs, three types of natural cores with typical carbonate pore structures were selected for high-temperature and high-pressure core displacement experiments. Fine quantitative characterization of the cores in three steady states (original, after sulfur injection, and after gas flooding) was carried out using the nuclear magnetic resonance (NMR) transverse relaxation time spectrum and imaging, X-ray computer tomography (CT) of full-diameter cores, basic physical property testing, and field emission scanning electron microscopy imaging. The loss of pore volume caused by sulfur deposition and adsorption mainly comes from the medium and large pores with sizes bigger than 1 000 μm. Liquid sulfur has a stronger adsorption and deposition ability in smaller pore spaces, and causes greater damage to reservoirs with poor original pore structures. The pore structure of the three types of carbonate reservoirs shows multiple fractal characteristics. The worse the pore structure, the greater the change of internal pore distribution caused by liquid sulfur deposition and adsorption, and the stronger the heterogeneity. Liquid sulfur deposition and adsorption change the pore size distribution, pore connectivity, and heterogeneity of the rock, which further changes the physical properties of the reservoir. After sulfur injection and gas flooding, the permeability of Type I reservoirs with good physical properties decreased by 16%, and that of Types II and III reservoirs with poor physical properties decreased by 90% or more, suggesting an extremely high damage. This indicates that the worse the initial physical properties, the greater the damage of liquid sulfur deposition and adsorption. Liquid sulfur is adsorbed and deposited in different types of pore space in the forms of flocculence, cobweb, or retinitis, causing different changes in the pore structure and physical property of the reservoir.