Kinetic Parameters of Thermal Decomposition of Biofuels and Its Oil-Containing Composites

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Solid Fuel Chemistry Pub Date : 2024-04-04 DOI:10.3103/S0361521924010063
A. A. Ponomareva, D. D. Laryushkina, D. A. Logacheva, V. E. Sitnikova, S. N. Mokrin, M. V. Uspenskaya
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Abstract

The kinetic features of the decomposition of fuel pellets formed from birch phloem and its composites with the addition of oil-containing waste (OCW) were studied by methods of thermogravimetric analysis carried out in various atmospheric conditions. The characteristic temperature ranges of thermal decomposition of the materials from which pellets are formed were identified. The rates of mass loss and activation energy at the main stages of thermal decomposition were evaluated. And the combustion indices of composite compositions were determined to identify the possibility of using such compositions as alternative fuels. By evaluating activation energies for each stage of sample decomposition, the limiting influence of certain stages of the thermal destruction process was established.

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生物燃料及其含油复合材料的热分解动力学参数
摘要 在各种大气条件下,通过热重分析方法研究了由桦树韧皮部及其复合材料(添加含油废物(OCW))形成的燃料颗粒的分解动力学特征。确定了形成颗粒的材料热分解的特征温度范围。评估了热分解主要阶段的质量损失率和活化能。此外,还确定了复合成分的燃烧指数,以确定将此类成分用作替代燃料的可能性。通过评估样品分解各阶段的活化能,确定了热破坏过程中某些阶段的限制性影响。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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