Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer

IF 2.3 4区 化学 Q2 Agricultural and Biological Sciences Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2024-04-11 DOI:10.1007/s10847-024-01238-0
Sotaro Kusumoto, Youssef Atoini, Yoshihiro Koide, Shinya Hayami, Yang Kim, Jack Harrowfield, Pierre Thuéry
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Abstract

The zwitterionic dicarboxylate 1,1′-[(2,3,5,6-tetramethylbenzene-1,4-diyl)bis(methylene)]bis(pyridin-1-ium-4-carboxylate) (L) has been reacted with uranyl nitrate under solvo-hydrothermal conditions and in the presence of KReO4 to give the complex [UO2(L)(OH)(H2O)](ReO4) (1). This compound crystallizes as a cationic, monoperiodic coordination polymer with ReO4 as a simple counterion. The daisy-chain polymer is based on dinuclear rings built by the convergent zwitterionic ligands, these rings being linked to one another by double hydroxide bridges. In addition to a Coulombic interaction with a pyridinium ring, ReO4 is involved in one OH(water)⋅⋅⋅O and four CH⋅⋅⋅O interactions, and it is thus nestled in a cavity formed by three chains, seemingly with some selectivity over nitrate and chloride anions also present in the reaction mixture. This result illustrates the interest of zwitterionic dicarboxylates in building cationic assemblies able to trap ReO4, a surrogate for the radioactive TcO4, an anion of environmental relevance.

Graphical abstract

A zwitterionic dicarboxylate ligand was reacted with the uranyl ion to generate a cationic, daisychain coordination polymer including perrhenate as counterion. Examination of the Hirshfeld surface of the anion allows for an analysis of the weak interactions involved.

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将铼酸阴离子封装在铀酰离子--齐聚物二羧酸配位聚合物中
1,1′-[(2,3,5,6- 四甲基苯-1,4-二基)双(亚甲基)]双(吡啶-1-鎓-4-羧酸盐)(L) 与硝酸铀酰在溶液-水热条件下和 KReO4 的存在下发生反应,得到复合物 [UO2(L)(OH)(H2O)](ReO4)(1)。这种化合物结晶成阳离子单周期配位聚合物,ReO4- 是简单的反离子。该菊花链聚合物基于由收敛的齐聚离子配体构建的双核环,这些环通过双氢氧桥相互连接。除了与一个吡啶鎓环的库伦相互作用外,ReO4- 还参与了一次 OH(水)-⋅⋅O 和四次 CH⋅⋅O 相互作用,因此它被嵌套在由三条链形成的空腔中,似乎对反应混合物中的硝酸根和氯离子具有一定的选择性。这一结果表明,在构建能够捕获 ReO4- 的阳离子组装体方面,齐聚二羧酸盐具有重要意义。图解摘要一种齐聚二羧酸盐配体与铀酰离子反应生成了一种阳离子菊花链配位聚合物,其中包括作为反离子的过铼酸盐。通过研究阴离子的 Hirshfeld 表面,可以分析其中的弱相互作用。
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来源期刊
CiteScore
3.30
自引率
8.70%
发文量
0
审稿时长
3-8 weeks
期刊介绍: The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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