Effect of TiO2 Crystal Facet on Pd/Anatase Catalysts for Formaldehyde Oxidation

IF 2.8 3区 化学 Q2 CHEMISTRY, APPLIED Topics in Catalysis Pub Date : 2024-04-03 DOI:10.1007/s11244-024-01943-7
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Abstract

Crystal facet engineering is an effective strategy for designing efficient catalysts to improve the ability to oxidize formaldehyde (HCHO). In this article, anatase TiO2 samples with different main exposed crystal facets ((001), (010) and (101)) were prepared and utilized as supports to load Pd, leading to the synthesis of Pd/TiO2 (001), Pd/TiO2 (010) and Pd/TiO2 (101) catalysts, respectively. For HCHO oxidation, Pd/TiO2 (001) displayed the best activity, and could convert 100% HCHO at 35 °C. However, the removal rates for Pd/TiO2 (010) and Pd/TiO2 (101) catalysts were only 46% and 35% even at 55 °C. After carefully comparing the property differences of these three supports, it was found that more surface defects were formed on the (001) facet than on (010) and (101). With more surface defects of support, Pd/TiO2 (001) catalyst possessed more oxygen vacancies, Pd metal sites and interface sites, which could effectively activate oxygen and water. This further improved the ability to oxidize HCHO. The findings from this study are anticipated to contribute valuable insights for the design of highly efficient supported noble metal catalysts.

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TiO2 晶面对 Pd/Anatase 甲醛氧化催化剂的影响
摘要 晶体面工程是设计高效催化剂以提高甲醛(HCHO)氧化能力的有效策略。本文制备了具有不同主要暴露晶面((001)、(010)和(101))的锐钛型二氧化钛样品,并将其作为负载钯的载体,分别合成了 Pd/TiO2 (001)、Pd/TiO2 (010) 和 Pd/TiO2 (101) 催化剂。在 HCHO 氧化过程中,Pd/TiO2 (001) 的活性最好,在 35 °C 时可以 100% 转化 HCHO。然而,即使在 55 ℃ 时,Pd/TiO2(010)和 Pd/TiO2(101)催化剂的去除率也仅为 46%和 35%。在仔细比较了这三种载体的性质差异后发现,(001) 面上形成的表面缺陷比 (010) 和 (101) 面上的要多。由于载体表面缺陷较多,Pd/TiO2 (001) 催化剂具有更多的氧空位、钯金属位和界面位,可有效活化氧和水。这进一步提高了氧化 HCHO 的能力。本研究的结果有望为设计高效的支撑贵金属催化剂提供有价值的见解。 图表摘要
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来源期刊
Topics in Catalysis
Topics in Catalysis 化学-物理化学
CiteScore
5.70
自引率
5.60%
发文量
197
审稿时长
2 months
期刊介绍: Topics in Catalysis publishes topical collections in all fields of catalysis which are composed only of invited articles from leading authors. The journal documents today’s emerging and critical trends in all branches of catalysis. Each themed issue is organized by renowned Guest Editors in collaboration with the Editors-in-Chief. Proposals for new topics are welcome and should be submitted directly to the Editors-in-Chief. The publication of individual uninvited original research articles can be sent to our sister journal Catalysis Letters. This journal aims for rapid publication of high-impact original research articles in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis.
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