Production of silicon by microwave heating

IF 1.6 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Isij International Pub Date : 2024-04-09 DOI:10.2355/isijinternational.isijint-2023-382
Kazuhiro Nagata, Hiroyuki Horikoshi
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Abstract

Mixed powder of SiO2 and SiC was heated to produce Si in air by irradiating multi-mode microwave at 2.45 GHz using a porous alumina crucible of sintered cement. SiC generated heat inside the mixture. Mullite layer was produced inside of crucible wall. Molten Si was produced at the apparent temperature between 1550°C and 1600°C during 5400s and 6000s. The apparent temperature was much lower than 1778°C determined thermodynamically. This is the characteristics of microwave that heat generates at the contact points of particles and the pointed parts of the surface in powder. A furnace for producing high-quality Si by microwave heating is proposed.

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通过微波加热生产硅
使用烧结水泥的多孔氧化铝坩埚,通过 2.45 GHz 的多模微波辐照,加热二氧化硅和碳化硅的混合粉末,在空气中生成硅。碳化硅在混合物内部产生热量。坩埚壁内产生莫来石层。在 5400s 和 6000s 期间,熔融硅的表观温度在 1550°C 和 1600°C 之间。表观温度远低于热力学温度 1778°C。这是微波在颗粒接触点和粉末表面尖锐部分产生热量的特点。提出了一种利用微波加热生产高质量硅的熔炉。
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来源期刊
Isij International
Isij International 工程技术-冶金工程
CiteScore
3.40
自引率
16.70%
发文量
268
审稿时长
2.6 months
期刊介绍: The journal provides an international medium for the publication of fundamental and technological aspects of the properties, structure, characterization and modeling, processing, fabrication, and environmental issues of iron and steel, along with related engineering materials.
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