{"title":"Production of silicon by microwave heating","authors":"Kazuhiro Nagata, Hiroyuki Horikoshi","doi":"10.2355/isijinternational.isijint-2023-382","DOIUrl":null,"url":null,"abstract":"</p><p>Mixed powder of SiO<sub>2</sub> and SiC<sub> </sub>was heated to produce Si in air by irradiating multi-mode microwave at 2.45 GHz using a porous alumina crucible of sintered cement. SiC generated heat inside the mixture. Mullite layer was produced inside of crucible wall. Molten Si was produced at the apparent temperature between 1550°C and 1600°C during 5400s and 6000s. The apparent temperature was much lower than 1778°C determined thermodynamically. This is the characteristics of microwave that heat generates at the contact points of particles and the pointed parts of the surface in powder. A furnace for producing high-quality Si by microwave heating is proposed.</p>\n<p></p>","PeriodicalId":14619,"journal":{"name":"Isij International","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Isij International","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.2355/isijinternational.isijint-2023-382","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
Mixed powder of SiO2 and SiCwas heated to produce Si in air by irradiating multi-mode microwave at 2.45 GHz using a porous alumina crucible of sintered cement. SiC generated heat inside the mixture. Mullite layer was produced inside of crucible wall. Molten Si was produced at the apparent temperature between 1550°C and 1600°C during 5400s and 6000s. The apparent temperature was much lower than 1778°C determined thermodynamically. This is the characteristics of microwave that heat generates at the contact points of particles and the pointed parts of the surface in powder. A furnace for producing high-quality Si by microwave heating is proposed.
期刊介绍:
The journal provides an international medium for the publication of fundamental and technological aspects of the properties, structure, characterization and modeling, processing, fabrication, and environmental issues of iron and steel, along with related engineering materials.