Pub Date : 2025-10-09DOI: 10.2355/isijinternational.isijint-2025-086
Guoliang Feng, Jintao Gao, Xi Lan, Lei Guo, Zhancheng Guo
Achieving phase transformation from spinel to the vanadium-enriched phase with higher chemical activity of vanadium oxide is essential for the efficient extraction of vanadium resources in vanadium slag. However, there is a severe lack of thermodynamic data for the relevant systems, which hampers our understanding for phase relations of vanadium-enriched phases. In this study, the phase equilibria of the "FeO"-SiO2-CaO-V2O3-TiO2 system were investigated at 1400 °C and 1200 °C, and the corresponding phase diagrams were constructed. It was found from these phase diagrams that the vanadium-rich phase (V,Ti,Fe)2O3 with a higher chemical activity of vanadium oxide than Fe(V,Ti,Fe)2O4 was identified, but the decrease in temperature was detrimental to the crystallization of (V,Ti,Fe)2O3. On these bases, the phase transformation from Fe(V,Ti,Fe)2O4 to (V,Ti,Fe)2O3 was further investigated at 1400 °C. It was found that the phase transformation occurred in three stages: the Fe(V,Ti,Fe)2O4 stage, the coexistence stage of Fe(V,Ti,Fe)2O4 and (V,Ti,Fe)2O3, and the (V,Ti,Fe)2O3 stage, and the phase transformation from Fe(V,Ti,Fe)2O4 to (V,Ti,Fe)2O3 was fully completed when the w("FeO")/w(SiO2) ratio was lower than 0.8. In this study, the essential thermodynamic data of the relevant system are complemented, while the phase transformation results of vanadium-enriched phases provide theoretical guidance for the efficient extraction of vanadium resources from vanadium slag.
{"title":"Phase Diagrams of “FeO”–SiO<sub>2</sub>–CaO–V<sub>2</sub>O<sub>3</sub>–TiO<sub>2</sub> System and Phase Transformation of Vanadium-enriched Phases","authors":"Guoliang Feng, Jintao Gao, Xi Lan, Lei Guo, Zhancheng Guo","doi":"10.2355/isijinternational.isijint-2025-086","DOIUrl":"https://doi.org/10.2355/isijinternational.isijint-2025-086","url":null,"abstract":"Achieving phase transformation from spinel to the vanadium-enriched phase with higher chemical activity of vanadium oxide is essential for the efficient extraction of vanadium resources in vanadium slag. However, there is a severe lack of thermodynamic data for the relevant systems, which hampers our understanding for phase relations of vanadium-enriched phases. In this study, the phase equilibria of the \"FeO\"-SiO2-CaO-V2O3-TiO2 system were investigated at 1400 °C and 1200 °C, and the corresponding phase diagrams were constructed. It was found from these phase diagrams that the vanadium-rich phase (V,Ti,Fe)2O3 with a higher chemical activity of vanadium oxide than Fe(V,Ti,Fe)2O4 was identified, but the decrease in temperature was detrimental to the crystallization of (V,Ti,Fe)2O3. On these bases, the phase transformation from Fe(V,Ti,Fe)2O4 to (V,Ti,Fe)2O3 was further investigated at 1400 °C. It was found that the phase transformation occurred in three stages: the Fe(V,Ti,Fe)2O4 stage, the coexistence stage of Fe(V,Ti,Fe)2O4 and (V,Ti,Fe)2O3, and the (V,Ti,Fe)2O3 stage, and the phase transformation from Fe(V,Ti,Fe)2O4 to (V,Ti,Fe)2O3 was fully completed when the w(\"FeO\")/w(SiO2) ratio was lower than 0.8. In this study, the essential thermodynamic data of the relevant system are complemented, while the phase transformation results of vanadium-enriched phases provide theoretical guidance for the efficient extraction of vanadium resources from vanadium slag.","PeriodicalId":14619,"journal":{"name":"Isij International","volume":"65 12","pages":"1850-1859"},"PeriodicalIF":0.0,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.jstage.jst.go.jp/article/isijinternational/advpub/0/advpub_ISIJINT-2025-086/_pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-05-18DOI: 10.2355/isijinternational.isijint-2025-024
Zhang Chen, Kang Shao, Xiaobo He, Lijun Wang
In rare-earth steel continuous casting, researchers examined the role of cerium oxide (CeO2) in mold slag crystallization. Using single hot thermocouple technique (SHTT) and Raman spectroscopy, they investigated the CaO-SiO2-Al2O3-Na2O-CaF2-(CeO2) slag system. The CeO2 was found to reduce structural polymerization, increase substance migration rates, and promote slag crystallization. Applying Johnson-Mehl-Avrami (JMA) and modified JMA models revealed distinct crystallization behaviors. In isothermal conditions, the crystal growth mechanism transitioned from one-dimensional to three-dimensional as temperature increased. Non-isothermal analysis consistently showed three-dimensional crystal growth. The models quantified how CeO2 content influences crystallization kinetics, demonstrating altered growth patterns. As CeO2 increased to 3%, the isothermal crystallization activation energy rose from 153.59 to 302.58 kJ/mol, indicating enhanced crystallization drive. Under non-isothermal conditions, with cooling rates of 1 to 20 °C/s, the apparent activation energy ranged from -288.44 to -941.97 kJ/mol. The negative values suggest that accelerated cooling and increased CeO2 concentration reduce crystallization process inhibition.
{"title":"Crystallization Kinetics of Mold Slag Containing CeO<sub>2</sub> in Isothermal and Non-isothermal Process","authors":"Zhang Chen, Kang Shao, Xiaobo He, Lijun Wang","doi":"10.2355/isijinternational.isijint-2025-024","DOIUrl":"https://doi.org/10.2355/isijinternational.isijint-2025-024","url":null,"abstract":"In rare-earth steel continuous casting, researchers examined the role of cerium oxide (CeO2) in mold slag crystallization. Using single hot thermocouple technique (SHTT) and Raman spectroscopy, they investigated the CaO-SiO2-Al2O3-Na2O-CaF2-(CeO2) slag system. The CeO2 was found to reduce structural polymerization, increase substance migration rates, and promote slag crystallization. Applying Johnson-Mehl-Avrami (JMA) and modified JMA models revealed distinct crystallization behaviors. In isothermal conditions, the crystal growth mechanism transitioned from one-dimensional to three-dimensional as temperature increased. Non-isothermal analysis consistently showed three-dimensional crystal growth. The models quantified how CeO2 content influences crystallization kinetics, demonstrating altered growth patterns. As CeO2 increased to 3%, the isothermal crystallization activation energy rose from 153.59 to 302.58 kJ/mol, indicating enhanced crystallization drive. Under non-isothermal conditions, with cooling rates of 1 to 20 °C/s, the apparent activation energy ranged from -288.44 to -941.97 kJ/mol. The negative values suggest that accelerated cooling and increased CeO2 concentration reduce crystallization process inhibition.","PeriodicalId":14619,"journal":{"name":"Isij International","volume":"65 8","pages":"1145-1152"},"PeriodicalIF":0.0,"publicationDate":"2025-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.jstage.jst.go.jp/article/isijinternational/advpub/0/advpub_ISIJINT-2025-024/_pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Titanium-bearing blast furnace slag (TBFS), a byproduct of ironmaking processes, has long been discarded as waste, resulting in the squandering of valuable resources such as titanium. The recovery and effective utilization of TBFS hold immense significance and importance. This study reports a direct electrolysis method for synthesizing Ti5Si3 alloy from a TBFS/SiO2 mixture in molten CaCl2 at 950°C. A comprehensive investigation was conducted into the phase and morphological evolution during the electrolysis process, along with an analysis of the migration behavior of impurities such as Ca and Al present in TBFS. The synthesized Ti5Si3 alloy powder was systematically characterized and analyzed using scanning electron microscopy, transmission electron microscopy, and other techniques. The results reveal that the electrolysis process encompasses electrochemical deoxidation, in-situ alloying, and self-purification. Furthermore, this study achieved further purification of the Ti5Si3 alloy through vacuum laser rapid melting, effectively volatilizing and removing the residual impurity elements, resulting in an increase in the purity of Ti5Si3 alloy from 96.8% to 98.6%. The resultant Ti5Si3 alloy exhibits excellent corrosion resistance in phosphate buffer solution. In summary, this work provides a crucial technical paradigm and scientific theoretical foundation for the resourceful and value-added utilization of ironmaking solid waste, specifically TBFS.
{"title":"Resourceful Utilization of Ironmaking Waste: Synthesis of Ti<sub>5</sub>Si<sub>3</sub> Alloy from Titanium-Bearing Blast Furnace Slag","authors":"Zhongya Pang, Shun Chen, Zhenqiang Jiang, Chenyang Han, Xing Yu, Kai Zheng, Chaoyi Chen, Guangshi Li, Qian Xu, Xingli Zou, Xionggang Lu","doi":"10.2355/isijinternational.isijint-2024-282","DOIUrl":"https://doi.org/10.2355/isijinternational.isijint-2024-282","url":null,"abstract":"Titanium-bearing blast furnace slag (TBFS), a byproduct of ironmaking processes, has long been discarded as waste, resulting in the squandering of valuable resources such as titanium. The recovery and effective utilization of TBFS hold immense significance and importance. This study reports a direct electrolysis method for synthesizing Ti5Si3 alloy from a TBFS/SiO2 mixture in molten CaCl2 at 950°C. A comprehensive investigation was conducted into the phase and morphological evolution during the electrolysis process, along with an analysis of the migration behavior of impurities such as Ca and Al present in TBFS. The synthesized Ti5Si3 alloy powder was systematically characterized and analyzed using scanning electron microscopy, transmission electron microscopy, and other techniques. The results reveal that the electrolysis process encompasses electrochemical deoxidation, in-situ alloying, and self-purification. Furthermore, this study achieved further purification of the Ti5Si3 alloy through vacuum laser rapid melting, effectively volatilizing and removing the residual impurity elements, resulting in an increase in the purity of Ti5Si3 alloy from 96.8% to 98.6%. The resultant Ti5Si3 alloy exhibits excellent corrosion resistance in phosphate buffer solution. In summary, this work provides a crucial technical paradigm and scientific theoretical foundation for the resourceful and value-added utilization of ironmaking solid waste, specifically TBFS.","PeriodicalId":14619,"journal":{"name":"Isij International","volume":"65 3","pages":"460-469"},"PeriodicalIF":0.0,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.jstage.jst.go.jp/article/isijinternational/65/3/65_ISIJINT-2024-282/_pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147334234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-18DOI: 10.2355/isijinternational.isijint-2024-182
Rafael Magalhaes De Melo Freire, Shohei Uranaka, Eita Tochigi, Mitsuo Kimura, Tomoya Kawabata
The amount of martensite in austenitic stainless steels produced during plastic deformation at low temperatures is related to the reduction in hydrogen embrittlement resistance. A pre-strain at 4 K was employed in this work to produce strain-induced martensite (SIM) in the microstructure of SUS316L and its weldment to verify the changes in hydrogen embrittlement susceptibility through slow strain tensile (SSRT) tests in a high-pressure hydrogen environment. As the base metal specimens, the weld metal specimens, manufactured by gas tungsten arc welding (GTAW or TIG) were pre-strained at different levels (5%, 10%, and 15%) for comparison with the non-pre-strained condition. Analysis of the most degraded samples tested from -150 °C to 0 °C is conducted through fracture surface observations, lateral crack length measurement, and crack densities. It was possible to indicate that the pre-strain effect induced earlier crack nucleation in comparison to the situation observed in the non-pre-strained material. Moreover, the pre-existing martensite produced by the pre-strain at 4 K is responsible for earlier crack nucleation, leading to a loss in the hydrogen embrittlement resistance for the SSRT pre-strained base metal specimens.