Green synthesis of biomass-derived porous carbon with hierarchical pores and enhanced surface area for superior VOCs adsorption

Abstract

The release of volatile organic compounds (VOCs) during the production, storage, and transportation of petroleum and its derivatives can be hazardous to human health and lead to secondary pollution. Addressing this challenge, this study introduces a sustainable and low-energy approach for synthesizing high-efficiency porous carbon materials, leveraging the abundant and renewable watermelon rinds as a carbon source. The carbonization and activation processes were optimized to minimize energy consumption while maximizing adsorptive performance. In this research, watermelon rinds were used as a source of carbon production, and melamine phosphate (FR-MP) was employed as a modifying agent. The FR-MP modified porous biomass-derived activated carbon (PWAC) was created by subjecting it to physical milling, carbonization, and activation. This approach not only utilized a waste biomass effectively but also reduced the overall carbon footprint of the production process. An examination of the effects of FR-MP dosage on the pore structure, surface chemical properties, and VOCs adsorption abilities of PWAC revealed that a higher FR-MP dosage resulted in a wider range of pore sizes within PWAC. The incorporation of FR-MP intensified the development of internal porosity and pore expansion in PWAC. Specifically, the optimized PWAC-0.3 exhibited a significant increase in specific surface area (3149 m²/g) and pore volume (1.76 cm³/g), enhancing adsorption capacities for acetone and n-hexane up to 1046 mg/g and 760 mg/g, respectively. Furthermore, the PWAC demonstrated exceptional recyclability, maintaining 97% of its original adsorption capacity after five cycles, underscoring its sustainable and economic viability. The highly advanced hierarchical ultra-meso-macroporous structure of PWAC significantly reduced the diffusion resistance of VOCs, guaranteeing swift mass transfer and desorption of VOCs. Consequently, the developed PWAC represents a novel, cost-effective, and environmentally-friendly approach for VOCs adsorption, aligning with the principles of green chemistry and low-energy consumption. This research not only provides a promising solution for VOCs mitigation but also highlights the potential of waste biomass in producing high-performance carbon materials.