{"title":"Highly site-selective C(sp3)–H bond functionalization enabled by framework confinements","authors":"Yuping Wang, Feihe Huang","doi":"10.1016/j.checat.2024.100961","DOIUrl":null,"url":null,"abstract":"<p>Mimicking enzymes’ ability to orient substrates through nanoconfinement holds significant promise for the development of artificial catalysts with enhanced performance. Recently in <em>Chem</em>, a cyclodextrin-based metal-organic framework has been shown to undergo selective C–H bond activation in the presence of guest molecules upon photoirradiation, illustrating a crucial advance in replicating biological catalysis within artificial matrices.</p>","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":null,"pages":null},"PeriodicalIF":11.5000,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.checat.2024.100961","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Mimicking enzymes’ ability to orient substrates through nanoconfinement holds significant promise for the development of artificial catalysts with enhanced performance. Recently in Chem, a cyclodextrin-based metal-organic framework has been shown to undergo selective C–H bond activation in the presence of guest molecules upon photoirradiation, illustrating a crucial advance in replicating biological catalysis within artificial matrices.
期刊介绍：
Chem Catalysis is a monthly journal that publishes innovative research on fundamental and applied catalysis, providing a platform for researchers across chemistry, chemical engineering, and related fields. It serves as a premier resource for scientists and engineers in academia and industry, covering heterogeneous, homogeneous, and biocatalysis. Emphasizing transformative methods and technologies, the journal aims to advance understanding, introduce novel catalysts, and connect fundamental insights to real-world applications for societal benefit.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
