Influence of lithium on Cu-doped ZnO thin films fabricated via sol-gel spin coating technique for improved NO2 gas sensing applications

IF 1.7 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS Journal of Electroceramics Pub Date : 2024-04-19 DOI:10.1007/s10832-024-00350-4
K. K. Jasmi, T. Anto Johny, V. S. Siril, K. N. Madhusoodanan
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Abstract

We demonstrate the influence of lithium on copper-doped ZnO-based thin films for improved NO2 gas sensing applications fabricated via the sol-gel spin coating technique. Structure studies confirmed hexagonal wurtzite structure and morphological analysis showed evenly dispersed, agglomerated spherical particles with an average grain size ranging from 25.94 to 30.79 nm. Lithium-doped Cu-ZnO with more surface oxygen vacancies and a higher carrier density demonstrated outstanding NO2 gas sensitivity, excellent repeatability, excellent stability, and high selectivity at 210 °C. A possible gas-sensing mechanism is also discussed and correlated with structural, morphological, spectral, and electrical parameters.

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锂对通过溶胶-凝胶旋涂技术制备的掺铜氧化锌薄膜的影响,用于改进二氧化氮气体传感应用
我们展示了锂对铜掺杂氧化锌薄膜的影响,该薄膜是通过溶胶-凝胶旋涂技术制造的,用于改进二氧化氮气体传感应用。结构研究证实其为六方菱锰矿结构,形态分析表明其为均匀分散的团聚球形颗粒,平均粒径为 25.94 至 30.79 nm。锂掺杂的 Cu-ZnO 具有更多的表面氧空位和更高的载流子密度,在 210 ℃ 下具有出色的二氧化氮气体灵敏度、卓越的重复性、出色的稳定性和高选择性。此外,还讨论了可能的气体传感机制,并将其与结构、形态、光谱和电学参数联系起来。
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来源期刊
Journal of Electroceramics
Journal of Electroceramics 工程技术-材料科学:硅酸盐
CiteScore
2.80
自引率
5.90%
发文量
22
审稿时长
5.7 months
期刊介绍: While ceramics have traditionally been admired for their mechanical, chemical and thermal stability, their unique electrical, optical and magnetic properties have become of increasing importance in many key technologies including communications, energy conversion and storage, electronics and automation. Electroceramics benefit greatly from their versatility in properties including: -insulating to metallic and fast ion conductivity -piezo-, ferro-, and pyro-electricity -electro- and nonlinear optical properties -feromagnetism. When combined with thermal, mechanical, and chemical stability, these properties often render them the materials of choice. The Journal of Electroceramics is dedicated to providing a forum of discussion cutting across issues in electrical, optical, and magnetic ceramics. Driven by the need for miniaturization, cost, and enhanced functionality, the field of electroceramics is growing rapidly in many new directions. The Journal encourages discussions of resultant trends concerning silicon-electroceramic integration, nanotechnology, ceramic-polymer composites, grain boundary and defect engineering, etc.
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