Enhanced Performance of Fe/WO3 Terahertz Dielectric Lenses

IF 1.5 4区 材料科学 Q3 Chemistry Crystal Research and Technology Pub Date : 2024-04-18 DOI:10.1002/crat.202300331
Hazem Kholoqi Khanfar, Atef Fayez Qasrawi
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Abstract

Herein transparent iron nanosheets deposited by the ionic coating technique onto glass and WO3 dielectric lenses are studied and characterized. The thickness of Fe nanosheets is varied in the range of 70–350 nm. It is observed that the transmittance and reflectance of the Fe nanosheets are highly affected by the layer roughness. Coating of iron nanosheets onto WO3 dielectric lenses increases the light absorption of WO3 by more than 240 times and red-shifts the energy bandgap. Remarkable enhancements in the dielectric constant and in the optical conductivity are achieved via Fe coatings. In addition, iron coated dielectric lenses show higher terahertz cutoff limits varying in the range of 1.0–30 THz. Iron nanosheets remarkably increase the free charge carrier density and plasmon frequency in the infrared range of light. Moreover, the temperature dependent electrical conductivity shows high temperature stability and an increased electrical conductivity by more than 7 orders of magnitude by coating WO3 with 70 nm thick Fe nanosheets. The stability of the electrical conductivity at low temperatures and the wide range of terahertz cutoff limits in addition to the well-enhanced light absorbability makes the iron coated tungsten oxide dielectric lenses promising for multifunction optoelectronic applications.

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提高铁/氧化物三太赫兹介质透镜的性能
本文研究了通过离子镀膜技术沉积在玻璃和 WO3 介电透镜上的透明铁纳米片,并对其进行了表征。铁纳米片的厚度在 70-350 nm 范围内变化。研究发现,铁纳米片的透射率和反射率受层粗糙度的影响很大。在 WO3 介电透镜上涂覆铁纳米片可将 WO3 的光吸收率提高 240 倍以上,并使能带隙发生红移。铁涂层显著提高了介电常数和光导率。此外,铁涂层介质透镜显示出更高的太赫兹截止限,范围在 1.0-30 太赫兹之间。铁纳米片显著提高了红外光范围内的自由电荷载流子密度和等离子体频率。此外,在 WO3 上镀 70 nm 厚的铁纳米片后,随温度变化的电导率显示出很高的温度稳定性,电导率提高了 7 个数量级以上。低温下电导率的稳定性、较宽的太赫兹截止限值范围以及良好的光吸收能力,使铁涂层氧化钨介电透镜在多功能光电应用中大有可为。
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来源期刊
CiteScore
2.50
自引率
6.70%
发文量
121
审稿时长
1.9 months
期刊介绍: The journal Crystal Research and Technology is a pure online Journal (since 2012). Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of -crystal growth techniques and phenomena (including bulk growth, thin films) -modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals) -industrial crystallisation -application of crystals in materials science, electronics, data storage, and optics -experimental, simulation and theoretical studies of the structural properties of crystals -crystallographic computing
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Issue Information: Crystal Research and Technology 11'2024 Research on the Heterogeneous Deformation Behavior of Nickel Base Alloy Based on CPFEM Ca(Mo,W)O4 Solid Solutions Formation in CaMoO4-CaWO4 System Growth of YAG:Nd laser crystals by Horizontal Directional Crystallization in Protective Carbon-Containing Atmosphere Preparation and Photophysical Properties of Znq2 Metallic Nanomaterials
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