Study on characteristics of ammonia alkali white mud and mechanical properties of preparation of fluid solidified soil

IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Frontiers in Materials Pub Date : 2024-04-19 DOI:10.3389/fmats.2024.1390421
Shifeng Fu, Zhiquan Li, Guangtian Zhang, Biao Zhang, Yanjia Zhang
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Abstract

To address the challenges posed by the significant quantity of ammonia-alkali white mud, this study explores the preparation of fluid solidified soil using ammonia-alkali white mud, mineral powder, and fly ash. The findings reveal that ammonia-alkali white mud primarily comprises sulfate, carbonate, and soluble chloride salt, with an alkaline solution and a well-developed pore structure. Optimal fluid solidified soil formulation, comprising 30% white mud, 30% salt mud, 25% mineral powder, 10% fly ash, and 5% calcium oxide, yields a slurry fluidity of 176 mm and a compressive strength of 3.98 MPa at 28 days. Microscopic analysis highlights AFt and C-S-H gel as the principal hydration products of fluid solidified soil. The fine particles of calcium carbonate in ammonia-alkali white mud fill the structural pores and intertwine with the hydration products, facilitating the formation of a dense structure, which constitutes the primary source of strength in fluid solidified soil. Furthermore, the heavy metal content of the solidified soil aligns with the first type of land use requirements outlined in the GB 36600-2018 standard, and the toxicity of the leaching solution adheres to the emission concentration limit stipulated by GB 8978-1996.
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氨碱白泥特性及流态固化土制备的力学性能研究
为应对大量氨碱白泥带来的挑战,本研究探索了利用氨碱白泥、矿粉和粉煤灰制备流态固化土的方法。研究结果表明,氨碱白泥主要由硫酸盐、碳酸盐和可溶性氯盐组成,溶液呈碱性,孔隙结构发达。最佳流体固化土壤配方由 30% 的白泥、30% 的盐泥、25% 的矿粉、10% 的粉煤灰和 5% 的氧化钙组成,28 天时泥浆流动性为 176 毫米,抗压强度为 3.98 兆帕。显微分析显示,AFt 和 C-S-H 凝胶是流态固化土壤的主要水化产物。氨碱白泥中细小的碳酸钙颗粒填充了结构孔隙,并与水化产物交织在一起,促进了致密结构的形成,这构成了流态固结土强度的主要来源。此外,固化土的重金属含量符合 GB 36600-2018 标准中规定的第一类土地利用要求,浸出液的毒性符合 GB 8978-1996 规定的排放浓度限值。
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来源期刊
Frontiers in Materials
Frontiers in Materials Materials Science-Materials Science (miscellaneous)
CiteScore
4.80
自引率
6.20%
发文量
749
审稿时长
12 weeks
期刊介绍: Frontiers in Materials is a high visibility journal publishing rigorously peer-reviewed research across the entire breadth of materials science and engineering. This interdisciplinary open-access journal is at the forefront of disseminating and communicating scientific knowledge and impactful discoveries to researchers across academia and industry, and the public worldwide. Founded upon a research community driven approach, this Journal provides a balanced and comprehensive offering of Specialty Sections, each of which has a dedicated Editorial Board of leading experts in the respective field.
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