Suppressing the damage of deposited Mn(II) ions to graphite anode in lithium-ion batteries by electrolyte additive agent and positive material coating

Abstract

SEM and EDS techniques are carried out to demonstrate the variation of morphology and chemical compound on the surface of graphite anode, which suggest a well-accepted concept that the manganese ions have serious influence on the reversible capacity fade of graphite anode in lithium ion batteries. Based the main chemical compounds of the inorganic layer on the graphite surface, the evolution steps of graphite structure damaged by Mn ions are derived. Although the amount of deposited manganese ions is small, these play an important role in the catalytic decomposition of the electrolyte. Moreover, Raman analysis shows that the structure of the graphite anode becomes irregular at initial SEI formation cycles and tends to be stable at subsequent cycles. This structure variation is probably generated from the manganese ion deposition and the solid electrolyte interphase (SEI) film formation. According to the capacity tests, the cycling performance of NCM811/graphite lithium-ion batteries could be improved 50% by FEC additive and B₂O₃ surface coating. FEC additive maybe benefit graphite forming a stable SEI film in the early stages of cycling to suppress the damage of Mn²⁺ ions, then improving the cycling performance.