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Heat Transfer Optimization of a Metal Hydride Tank Targeted to Improve Hydrogen Storage Performance
Pub Date : 2024-12-18 DOI: 10.1002/est2.70099
Nadhir Lebaal, Djafar Chabane, Alaeddine Zereg, Noureddine Fenineche

In this study, the optimization of heat transfer in a metal hydride hydrogen tank to maximize hydrogen storage was investigated. A finite element model of a quarter tank was developed in COMSOL Multiphysics with parameterized geometry. The main objectives were to maximize stored hydrogen mass and minimize tank filling time while maintaining temperature uniformity within the tank. A design of experiments (DOE) approach was used with key geometrical parameters. Compared to the base case, the hydrogen stored mass increased from 0.26 to 0.46 kg, and the tank filling time reduced from over 1100 to 450 s. The optimal design (Design point 15) resulted in an absorbed hydrogen mass of 0.4624 kg, with a charging time of 450 s, showing the most balanced performance in terms of maximizing storage while minimizing filling time and better heat dissipation. This demonstrates the potential of optimizing heat transfer to significantly improve metal hydride hydrogen storage performance. The model can be further improved by exploring different cooling designs and materials.

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引用次数: 0
Polyaniline/Reduced Graphene Oxide/Zinc Oxide Hybrid Electrodes Fabricate by Combining Electrospinning/Electrospray Technique for Supercapacitors
Pub Date : 2024-12-12 DOI: 10.1002/est2.70101
Shilpa Simon, P. B. Sreeja

This study presents the successful synthesis and characterization of polyaniline (PANI), PANI/reduced graphene oxide PANI/rGO (PR), and PANI/rGO/ZnO (PRZ) nanocomposites as electrode materials for supercapacitors. Employing electrospinning and electrospraying techniques, we developed nanofibrous composites with enhanced structural and electrochemical properties. The addition of rGO and ZnO in the PRZ composite significantly improved specific capacitance, stability, and charge-transfer efficiency. Electrochemical analyses, including cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS), revealed a peak specific capacitance of 845 F g−1 at 0.5 A g−1 for PRZ, outperforming PR (395 F g−1), and PANI (140 F g−1). These enhancements are attributed to the synergistic effects of carbon-based and pseudocapacitive components, resulting in higher conductivity, improved redox activity, and reduced internal resistance. Additionally, the PRZ composite exhibited excellent cyclic stability, retaining 89% of its capacitance over 5000 cycles, underscoring its durability and suitability for long-term energy storage applications.

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引用次数: 0
Search Survive Optimization Based Deep Incorporated Model for Electric Vehicle Battery Fault Detection 基于搜索生存优化的电动汽车电池故障深度检测模型
Pub Date : 2024-12-12 DOI: 10.1002/est2.70073
Shashank Kumar Jha, Sumit Kumar Jha, Bishnu Mohan Jha

With the progressive switching from a conventional transportation system to an intelligent transportation system (ITS), the eco-friendly alternative is made possible in metro cities. Moreover, electric vehicles (EVs) gained more attention due to their low charging costs, low energy consumption, and reduced greenhouse gas emissions. However, a single failure or malfunction in an EV's intrinsic components due to poor charging infrastructure can bring about a high tendency of fault occurrence that needs to be diagnosed earlier for efficient safety management. In addition, ensuring the safety and reliability of these EV batteries remains a critical challenge that underscores the importance of an efficient battery fault detection system, pivotal in enhancing battery safety and lifespan. Hence, the research centers on developing a well-structured battery fault detection model leveraging a Search- Survive optimization (SSO) based deep incorporated model. This incorporated model combines Deep Convolutional Neural Network (Deep CNN), Deep Bidirectional Long-Short Term Memory (Deep BiLSTM), and Deep Belief Network (DBN) that assists in extracting the hierarchical representations and the spatial–temporal features associated with the various EV faults. The deep incorporated model is optimized with SSO that aids the model to perform enhanced battery fault detection of EVs. Performance assessment relies on key parameters like accuracy, sensitivity, and specificity, based on the NASA battery dataset. Impressively, the SSO-based Deep Incorporated model attains an accuracy of 96.00%, sensitivity of 96.29%, and specificity of 95.72 for 80% of training. With k-fold 10 validation, the proposed model attained the metric values of 96.31%, 97.29%, and 95.32% respectively using the NASA dataset and surpassed other existing techniques.

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引用次数: 0
Parametric Investigation to Assess the Charging and Discharging Time for a Latent Heat Storage Material-Based Thermal Energy Storage System for Concentrated Solar Power Plants 评估聚光太阳能发电站潜热存储材料热能存储系统充放电时间的参数调查
Pub Date : 2024-12-12 DOI: 10.1002/est2.70102
Ramesh Rudrapati, Santosh Chavan, Sung Chul Kim

Thermal energy storage (TES) systems are becoming increasingly crucial as viable alternatives for effective energy utilization from various sources, such as solar power plants and waste heat from different industrial sectors. The present work focuses on latent heat TES system optimization for solar thermal power plant applications. This study aims to assess the impact of different thermal processing factors on the efficiency of TES systems. Parametric analysis determines a TES system's charging and discharging durations that use latent heat storage material. Thermal processing conditions were selected as input parameters, such as the heat transfer fluid inlet temperature, flow rate, and number of phase change material (PCM) capsules. Experiments were planned to use the L9 orthogonal array of the Taguchi method, and response measures, such as charging time (CT) and discharging time (DT), were monitored. A signal-to-noise ratio analysis was used to evaluate the significance of the thermal processing parameters on the response measures. Response surface methodology (RSM) postulates the mathematical relationships between process conditions and responses. Finally, the multi-objective Jaya optimization algorithm (MOJOA) was used to optimize the parametric combination to minimize CT and maximize DT simultaneously. A heat transfer fluid inlet temperature of 65°C, flow rate of 2 L/min, and 40 PCM capsules were determined as the optimal parametric conditions by MOJOA for predicting the combined CT and DT. The verification test results substantiate the enhanced responses of the latent heat TES system, specifically in the CT and DT. Utilizing the integrated Taguchi method, RSM-MOJOA is advantageous for examining, modeling, and predicting PCM-based TES systems.

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引用次数: 0
Enhanced Thermoelectric Performance of La1.98Sr0.02Cu0.94Co0.06O4 by Multiwalled Carbon Nanotubes Addition
Pub Date : 2024-12-03 DOI: 10.1002/est2.70098
Mohd Saif, D. Tripathi

Effect of multiwalled carbon nanotubes (MWCNTs) addition on thermoelectric properties of polycrystalline LSCCO (La1.98Sr0.02Cu0.94Co0.06O4) has been examined. The samples have been synthesized via the solid-state reaction technique. Micro-structural and surface morphology of the synthesized pellets have been investigated using X-ray diffraction and Field Emission Scanning Electron Microscopy, respectively. The electrical resistivity and Seebeck coefficient of investigated pellets have been measured using a custom-built apparatus between 300 and 450 K. Nevertheless, the transient heat transfer technique has been adopted for thermal conductivity measurement. The addition of MWCNTs significantly enhances the electrical conductivity and reduces the thermal conductivity of LSCCO. This results in a remarkable improvement in the figure of merit in spite of the reduction in Seebeck coefficient with MWCNTs addition. The maximum ZT value ~0.07 is achieved at 323 K for 0.05 wt% MWCNTs-loaded LSCCO, which is ~28 times that of pristine LSCCO. The enhanced thermoelectric performance is attributed to the increased carrier concentration, reduced grain size, and improved interface phonon scattering due to MWCNTs addition. Our results demonstrate the potential of MWCNTs as an effective additive to enhance the thermoelectric properties of LSCCO-based materials.

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引用次数: 0
A System to Store Waste Heat as Liquid Hydrogen Assisted by Organic Rankine Cycle, Proton Exchange Membrane Electrolyzer, and Mixed Refrigerant Hydrogen Liquefaction Cycle 利用有机朗肯循环、质子交换膜电解槽和混合制冷剂氢液化循环将废热储存为液氢的系统
Pub Date : 2024-11-24 DOI: 10.1002/est2.70064
Abolfazl Nikzad, Mostafa Mafi, Saman Faramarzi

This study proposes a system to store waste heat as liquid hydrogen using a proton exchange membrane electrolyzer (PEME) and a mixed refrigerant hydrogen liquefaction cycle. The novelty of this study lies in proposing a waste heat recovery system that stores electricity as liquid hydrogen, consuming less power due to the improved exergy efficiency of the components. The proposed system is analyzed to achieve better efficiency in terms of thermal and exergy efficiencies. Waste heat is used to generate power by an organic Rankin cycle (ORC), produced electricity is utilized in the PEME unit and compressors of liquefaction cycle to produce and liquefy hydrogen, respectively. Codes are written in EES software to simulate the system. Thermodynamic analysis is done in order to achieve better thermal efficiency for the proposed model. Membrane potential at different values of current density is calculated and compared with validate the simulated model. The exergy efficiency of the liquid hydrogen production process is 57%. The exergy efficiency, rate of power produced in ORC, and rate of hydrogen production by the electrolyzer increase significantly by increasing the isentropic efficiency of the turbine. At a temperature of 340 K for the evaporator, the thermal efficiency of ORC is obtained at 8.5%, which is approximately 3% higher compared with that of the previous similar process.

本研究提出了一种利用质子交换膜电解槽(PEME)和混合制冷剂氢液化循环将废热储存为液氢的系统。本研究的新颖之处在于提出了一种废热回收系统,该系统可将电能储存为液态氢,由于提高了各组件的放能效率,因此消耗的电能更少。通过分析所提出的系统,可以在热效率和放能效率方面实现更高的效率。废热通过有机朗肯循环(ORC)产生电能,产生的电能分别用于 PEME 装置和液化循环的压缩机,以生产和液化氢气。用 EES 软件编写了模拟系统的代码。进行热力学分析是为了使所提出的模型获得更好的热效率。计算了不同电流密度值下的膜电位,并与模拟模型进行比较验证。液氢生产过程的放能效率为 57%。通过提高涡轮机的等熵效率,放能效率、ORC 的发电率和电解槽的制氢率都显著提高。在蒸发器温度为 340 K 时,ORC 的热效率为 8.5%,与之前的类似工艺相比提高了约 3%。
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引用次数: 0
Sustainable Hydrogen Storage and Methanol Synthesis Through Solar-Powered Co-Electrolysis Using SOEC 利用 SOEC 进行太阳能供电的共电解,实现可持续的氢气储存和甲醇合成
Pub Date : 2024-11-21 DOI: 10.1002/est2.70095
Muhammad Sajid Khan, Muhammad Abid, Chen Chen, Juliana Hj Zaini, Tahir Ratlamwala, Ali Ahmed Alqahtani

Syngas rich in hydrogen, generated through renewable-powered co-electrolysis of water (H2O) and carbon dioxide (CO2) using solid oxide electrolysis cells (SOEC), have gained significant attention due to its high efficiency and conversion rates. This method offers a promising solution for mitigating global warming and reducing CO2 emissions by enabling the storage of intermittent renewable energy. This study investigates solar-integrated co-electrolysis of H2O and CO2 via SOEC to produce hydrogen-rich syngas, which is then utilized for methanol synthesis through a series of heat exchangers and compressors. Parabolic dish solar collectors supply thermal energy, while photovoltaic modules provide electricity for SOEC operation. CO2 from industrial processes is captured and combined with steam at the SOEC inlet for co-electrolysis. The proposed system is modeled using engineering equation solver software, incorporating mass, energy, and exergy balance equations. The system's performance is analyzed by varying key parameters such as direct normal irradiance, heat exchanger effectiveness, current density, cell temperature, and pressure. The proposed system achieves a solar-to-fuel efficiency of 29.1%, with a methanol production rate of 41.5 kg per hour. Furthermore, an economic analysis was conducted to determine the levelized cost of fuel.

通过使用固体氧化物电解槽(SOEC)对水(H2O)和二氧化碳(CO2)进行可再生动力共电解而产生的富含氢气的合成气,因其高效率和转换率而备受关注。这种方法通过储存间歇性可再生能源,为缓解全球变暖和减少二氧化碳排放提供了一种前景广阔的解决方案。本研究通过 SOEC 研究了太阳能集成的 H2O 和 CO2 共电解,以产生富氢合成气,然后通过一系列热交换器和压缩机将其用于合成甲醇。抛物面碟形太阳能集热器提供热能,而光伏组件则为 SOEC 的运行提供电力。工业生产过程中产生的二氧化碳被收集起来,在 SOEC 入口处与蒸汽结合进行共电解。拟议系统使用工程方程求解软件建模,其中包含质量、能量和放能平衡方程。通过改变直接法线辐照度、热交换器效率、电流密度、电池温度和压力等关键参数,对系统性能进行了分析。拟议系统的太阳能转化为燃料的效率为 29.1%,甲醇生产率为每小时 41.5 公斤。此外,还进行了经济分析,以确定燃料的平准化成本。
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引用次数: 0
Strategic Patent Portfolio Management in the Sodium-Ion Battery Industry: Navigating Innovation and Competition 钠离子电池行业的战略性专利组合管理:驾驭创新与竞争
Pub Date : 2024-11-19 DOI: 10.1002/est2.70097
Vinoth Kumar Jayaraman, Annigere S. Prakash

In the rapidly evolving landscape of energy storage technologies, sodium-ion batteries (SIBs) have emerged as promising alternatives to conventional lithium-ion batteries. SIBs exhibit moderate to high specific energy ranging from approximately 70 to 170 Wh/kg, ensuring suitability for diverse applications. Furthermore, with their abundance of raw materials and potential for lower costs, sodium-ion batteries are attracting significant interest from researchers, manufacturers, and investors. This heightened interest is evidenced by the exponential growth in the number of patents filed for SIBs, totalling 142 648 patents. This surge in patent filings underscores the growth pattern of SIBs as promising alternatives in the energy storage landscape. In this dynamic environment, securing and maintaining a robust patent portfolio is imperative for companies and innovators to establish a competitive edge, enabling them to capitalize on the increasing market demand. This perspective examines the strategies involved in building, protecting, and managing a robust patent portfolio as well as provides intellectual property challenges and patent filing opportunities in SIB technologies.

在快速发展的储能技术领域,钠离子电池(SIB)已成为传统锂离子电池的理想替代品。钠离子电池具有中等到较高的比能量,约为 70 到 170 Wh/kg,确保适合各种应用。此外,钠离子电池具有丰富的原材料和降低成本的潜力,正吸引着研究人员、制造商和投资者的浓厚兴趣。钠离子电池申请专利的数量呈指数级增长,总计达到 142 648 项,证明了这种兴趣的高涨。专利申请数量的激增凸显了 SIB 作为能源储存领域前景广阔的替代品的发展模式。在这种充满活力的环境中,企业和创新者必须确保并维持稳健的专利组合,才能建立竞争优势,抓住日益增长的市场需求。本视角探讨了建立、保护和管理稳健的专利组合所涉及的战略,并提供了 SIB 技术的知识产权挑战和专利申请机会。
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引用次数: 0
Optimizing Wind and Solar Integration in a Hybrid Energy System for Enhanced Sustainability 优化混合能源系统中的风能和太阳能集成,增强可持续性
Pub Date : 2024-11-18 DOI: 10.1002/est2.70096
Amir Hossein Forghani, Alireza Arab Solghar, Hassan Hajabdollahi

A hybrid energy system, comprising a diesel engine as the prime mover, electrical and absorption chillers, a backup boiler, and a multi-effect distillation through thermal vapor compression (MED-TVC) unit, has been utilized to meet the requirements of a residential complex. This study focuses on redesigning and optimizing the system to enhance environmental conditions, reduce pollutants, and minimize the use of fossil energy. The feasibility and design of renewable energy systems, including wind turbines (WTs), photovoltaic panels (PVs), and flat plate collectors (FPCs), have been examined. Genetic algorithm (GA) has been employed for optimization. The hybrid system employs 21 design variables, with 24 design variables chosen for optimization alongside renewable energies. The total annual cost (TAC), encompassing investment, operation, and pollution emission fines, has been chosen as the objective function for minimization. The results indicate that the use of WTs has not been cost-effective, and solar energy can enhance the system's performance in Bandar Abbas, Hormozgan province in Iran. In the case of using a combined system, the objective function value was 2.0472 × 106 $/year, and when using renewable energies, the objective function became 1.6795 × 106 $/year. Thus, the proposed combined-renewable system has reduced the objective function by 17.96%.

混合能源系统由作为原动机的柴油发动机、电制冷机和吸收式制冷机、备用锅炉以及通过热蒸汽压缩的多效蒸馏(MED-TVC)装置组成,已被用于满足一个住宅区的要求。本研究的重点是重新设计和优化该系统,以改善环境条件,减少污染物,并最大限度地减少化石能源的使用。研究考察了可再生能源系统的可行性和设计,包括风力涡轮机 (WT)、光电板 (PV) 和平板集热器 (FPC)。该系统采用遗传算法(GA)进行优化。混合系统采用了 21 个设计变量,其中 24 个设计变量与可再生能源一起用于优化。年度总成本(TAC)包括投资、运营和污染排放罚款,被选为最小化的目标函数。结果表明,在伊朗霍尔木兹甘省的 Bandar Abbas,使用风力发电机并不符合成本效益,而太阳能可以提高系统的性能。在使用组合系统的情况下,目标函数值为 2.0472 × 106 美元/年,而在使用可再生能源的情况下,目标函数值为 1.6795 × 106 美元/年。因此,拟议的组合式可再生能源系统将目标函数值降低了 17.96%。
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引用次数: 0
Design and Simulation of Flat Plate Collector With a Tube Rotation and Phase Change Materials Sn3N4-LiNO3-KNO3/Boron-Arsenide for Enhanced Efficiency 设计和模拟带有管旋转和相变材料 Sn3N4-LiNO3-KNO3/Boron-Arsenide 的平板集热器以提高效率
Pub Date : 2024-11-17 DOI: 10.1002/est2.70084
Muhammad Shehram, Talha Farooq

Solar thermal energy is crucial in our transition to renewable energy sources. Recent studies have focused on enhancing the efficiency of solar collectors by minimizing thermal energy loss during absorption. A promising approach involves an innovative design that integrates phase change materials (PCMs) and rotating tubes to capture thermal energy more effectively. Advanced nitride-based salt hydrates, with boron-arsenide additives, enhance thermal performance of the collector. In a flat plate collector using composite PCMs, radiative heat loss decreases from 250 to 210 W (a 6% reduction) with tube rotation, while convective heat loss drops from 225 to 195 W (a 4% decrease). The decomposition rate of the novel PCMs is low, measuring only 0.5% at a maximum temperature of 850°C, with a specific heat capacity of up to 4.50 W/m K. This unique blend, including the Sn₃N₄-LiNO₃-KNO₃/boron arsenide mixture, enhances thermal conductivity by 30%, significantly improving thermal absorption rates. The exergy efficiency achieved with the Nano-enhanced phase change materials (NEPCM) and tube rotation reaches an impressive 90%. With tube rotation at 3 rad/min, the flat plate collector's efficiency improves by 22%, reaching an overall efficiency of 90% at a fluid flow rate of 25 kg/h. Simulations using Anaconda Jupyter Notebook and Python validate the effectiveness of both tube rotation and NEPCM in enhancing collector efficiency.

在向可再生能源过渡的过程中,太阳能热能至关重要。最近的研究重点是通过最大限度地减少吸收过程中的热能损失来提高太阳能集热器的效率。一种很有前景的方法是采用创新设计,将相变材料(PCM)和旋转管整合在一起,从而更有效地捕获热能。先进的氮基盐水合物以及硼砷化物添加剂可提高集热器的热性能。在使用复合 PCM 的平板集热器中,随着管子的旋转,辐射热损失从 250 瓦减少到 210 瓦(减少 6%),而对流热损失从 225 瓦减少到 195 瓦(减少 4%)。这种独特的混合物(包括锡₃N₄-LiNO₃-KNO₃/砷化硼混合物)将热传导率提高了 30%,显著提高了热吸收率。利用纳米增强相变材料(NEPCM)和管道旋转实现的能效达到了令人印象深刻的 90%。当管子以 3 弧度/分钟的速度旋转时,平板集热器的效率提高了 22%,在流体流速为 25 公斤/小时的情况下,总效率达到 90%。使用 Anaconda Jupyter Notebook 和 Python 进行的模拟验证了管旋转和 NEPCM 在提高集热器效率方面的有效性。
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引用次数: 0
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Energy Storage
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