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Performance Analysis of a Renewable-Powered Multi-Gas Floating Storage and Regasification Facility for Ammonia Vessels With Reconversion to Hydrogen 用于氨船的可再生能源多气体浮式储存和再气化设施的性能分析与氢气再转换
Pub Date : 2024-09-12 DOI: 10.1002/est2.70033
Dindha Andriani, Muhammad Usman Sajid, Yusuf Bicer

Natural gas and renewable energy carriers play critical roles in the energy supply chain due to rising energy consumption demands and a significant shift toward cleaner energy. However, the requirement to liquefy and regasify liquefied natural gas (LNG) and renewable energy carriers for transportation makes the entire process expensive and challenging. Hence, a floating storage and regasification unit (FSRU) plant provides a solution to the aforementioned problems with the additional benefit of being more affordable, time-efficient, and having less land footprint requirement than the conventional onshore facility. The proposed integrated FSRU in this study, is powered by renewable energy, including solar and ocean thermal energy. The subsystems of integrated FSRU consist of parabolic dish collectors (PDC), Rankine cycle, organic Rankine cycle (ORC), multi-stage flashing (MSF) desalination unit, decomposition, reliquefication, and regasification plants, which provide valuable commodities such as freshwater, electricity, hydrogen, and heating. It can also cater to standard multi-gas harboring vessels for storage and regasification of sustainable energy carriers. The study assesses the performance of the proposed system thermodynamically by analyzing mass, energy, entropy, and exergy balance equations using the engineering equation solver (EES) software. Furthermore, parametric studies were conducted to understand the interlinkage among various variables. The analytical results show that the proposed system is able to produce 1.82 MW of electricity, 2056 kg/day of fresh water, and 338.3 kg/day of hydrogen, achieving an overall system energy efficiency of 32.7% and exergy efficiency of 79.3%. This approach aims to foster energy diversification, enhance energy security, and support the transition toward sustainable energy systems, as well as further the advancement of maritime transport systems.

由于能源消耗需求不断增长以及向清洁能源的重大转变,天然气和可再生能源运输船在能源供应链中发挥着至关重要的作用。然而,液化天然气(LNG)和可再生能源运输船在运输过程中需要液化和再气化,这使得整个过程既昂贵又具有挑战性。因此,浮式储存和再气化装置(FSRU)工厂为上述问题提供了一个解决方案,与传统的陆上设施相比,它还具有价格更低廉、时间效率更高、占地面积更少等额外优势。本研究中提议的一体化 FSRU 由可再生能源提供动力,包括太阳能和海洋热能。一体化 FSRU 的子系统包括抛物面碟形集热器 (PDC)、朗肯循环、有机朗肯循环 (ORC)、多级闪蒸 (MSF) 海水淡化装置、分解、再液化和再气化装置,可提供淡水、电力、氢气和供热等有价值的商品。它还能满足标准多气体港船对可持续能源载体的储存和再气化。本研究通过使用工程方程求解器(EES)软件分析质量、能量、熵和放能平衡方程,从热力学角度评估了拟议系统的性能。此外,还进行了参数研究,以了解各种变量之间的相互联系。分析结果表明,建议的系统能够生产 1.82 兆瓦的电力、2056 千克/天的淡水和 338.3 千克/天的氢气,系统整体能效达到 32.7%,放能效率达到 79.3%。这种方法旨在促进能源多样化,加强能源安全,支持向可持续能源系统过渡,并进一步推动海上运输系统的发展。
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引用次数: 0
An Innovative Energy Storage System Based on Phase Change Material and Solar Energy Integrated With an Air Handling Unit to Produce Heating and Cooling 基于相变材料和太阳能的创新型储能系统,与空气处理装置集成以产生暖气和冷气
Pub Date : 2024-09-12 DOI: 10.1002/est2.70031
Seyyed Amirreza Abdollahi, Saman Faramarzi, Seyyed Faramarz Ranjbar, Kazem Hashemi, Hamid Majidi, Ehsan Gholamian

This study investigates the potential of using phase change material (PCM) in a building using an air handling unit (AHU) assisted by solar energy. To further enhance the system, an energy storage system (ESS) can be considered. Implementing ESS would allow the captured solar energy to be stored efficiently, ensuring a continuous and reliable power source for cooling or heating the air, even during non-sunlight hours. The air-conditioned zone is considered to be 220 m2 in which 30 people work for 12 h a day. An energy analysis is conducted to evaluate the performance of the proposed system in terms of energy and exergy loss. The genetic algorithm (GA) method is used to optimize the system. The results indicate that the system, including PCM and solar system, can reduce energy consumption by up to 8.9% compared to conventional AHUs in the hottest month of the year (July). The results indicated that employing PCM leads to a decrease of 124 kWh in heat loss during January and 229 kWh in heat gain during July. Taking into account the beneficial impacts of both PCM and the solar system, the yearly assessment demonstrates a 2.69% reduction in power demand, equating to an energy saving of 679 kWh. Furthermore, PCM in the proposed system can be used in integration with AHUs based on renewable energy systems to store renewable energy for buildings.

本研究探讨了在太阳能辅助下在建筑物空气处理装置(AHU)中使用相变材料(PCM)的潜力。为了进一步增强该系统,可以考虑采用储能系统(ESS)。采用储能系统可以有效地储存捕获的太阳能,确保即使在非日照时间也能为空气冷却或加热提供持续可靠的动力源。空调区面积为 220 平方米,30 人每天工作 12 小时。我们进行了能源分析,以评估拟议系统在能源和放能损失方面的性能。采用遗传算法(GA)对系统进行优化。结果表明,在一年中最热的月份(7 月),包括 PCM 和太阳能系统在内的该系统比传统空调机组最多可减少 8.9% 的能耗。结果表明,采用 PCM 后,1 月份的热量损失减少了 124 千瓦时,7 月份的热量增加了 229 千瓦时。考虑到 PCM 和太阳能系统的有利影响,年度评估显示电力需求减少了 2.69%,相当于节省了 679 千瓦时的能源。此外,拟议系统中的 PCM 可与基于可再生能源系统的自动空调机组结合使用,为建筑物储存可再生能源。
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引用次数: 0
The Solid-State Battery Applicational Technology: Material Characteristics and Charge–Discharge Mechanisms of Iron Chloride Electrodes 固态电池应用技术:氯化铁电极的材料特性和充放电机制
Pub Date : 2024-09-12 DOI: 10.1002/est2.70044
Zhi-Yue Chen, Fei-Yi Hung, Kai-Chieh Chang

This study delves into the unique characteristics of an iron chloride cathode with a solid-state electrolyte (SSE) and the construction of a button cell battery (BT cell) for its evaluation. The iron ions in this system can provide either divalent or trivalent ions, which possess a higher electrical capacity (~200 mAh/g) and competitive advantages. The solid-state electrolyte materials, iron compounds (chloride, oxide), exhibit high activation in electrochemistry. After the cycle test, the ferric chloride electrolyte transforms into another iron hydroxide compound due to its high activation. The study examines iron, ferric oxide (Fe2O3), and ferrous chloride (FeCl2) as cathode materials and evaluates their impact on the battery. Cyclic voltammetry compares the potential and current values of the redox reactions among the three. Finally, transmission electron microscopy (TEM) explores the ferric chloride layer and iron hydroxide in ferrous chloride. The study focuses on the high electrochemical activity of the iron chloride layer and explores the crystal structure and composition for electrochemical analysis. The findings of this study are crucial for understanding the potential of iron-ion batteries and the role of iron compounds in improving battery performance.

本研究深入探讨了具有固态电解质(SSE)的氯化铁阴极的独特特性,并构建了纽扣电池(BT 电池)对其进行评估。该系统中的铁离子可提供二价或三价离子,具有更高的电容量(约 200 mAh/g)和竞争优势。固态电解质材料、铁化合物(氯化物、氧化物)在电化学中表现出较高的活化性。在循环测试后,氯化铁电解质会因高活性而转化为另一种氢氧化铁化合物。本研究考察了作为阴极材料的铁、氧化铁(Fe2O3)和氯化亚铁(FeCl2),并评估了它们对电池的影响。循环伏安法比较了三种材料氧化还原反应的电位和电流值。最后,透射电子显微镜(TEM)对氯化铁层和氯化亚铁中的氢氧化铁进行了研究。该研究重点关注氯化铁层的高电化学活性,并探索晶体结构和组成,以便进行电化学分析。这项研究的发现对于了解铁离子电池的潜力以及铁化合物在提高电池性能方面的作用至关重要。
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引用次数: 0
Hydrogen Storage Studies of Nanocomposites Derived From O-Ethyl-S-((5-Methoxy-1H-Benzo[d]Imidazol-2-Yl)Carbonothioate (OESMBIC) With ZnO and TiO2 Nanoparticles 由 O-乙基-S-((5-甲氧基-1H-苯并[d]咪唑-2-基)硫代碳酸酯 (OESMBIC) 与 ZnO 和 TiO2 纳米粒子衍生的纳米复合材料的储氢研究
Pub Date : 2024-09-11 DOI: 10.1002/est2.70039
Nuaman F. Alheety, Noureddine Raouafi, Abdulsalam A. Al-Isawi, Mustafa A. Alheety, Rafaâ Besbes

5-Methoxy-2-mercaptobenzamidazole was used to synthesize O-ethyl-S-(5-methoxy-1H-benzo[d]imidazol-2-yl) carbonothioate (OESMBIC) by the reaction with chloroacetic acid ethyl ester in a KOH solution. The reaction product (OESMBIC) was characterized using Fourier transform infrared (FTIR), melting point, and 1H-NMR. The characteristic results prove the formation of the target compound with high purity. Furthermore, the work includes the synthesis of ZnO and TiO2 nanoparticles via chemical methods in the high alkalinity solution. These nanoparticles were used to synthesize two novel nanocomposites named OESMBIC-ZnO and OESMBIC-TiO2. The synthesized nanocomposites were characterized by FTIR, SEM, EDX, TEM, and XRD. The results prove that the prepared titanium oxide as nanotubes with diameters ranging between 20 and 35 nm decorated with OESMBIC. The results prove that ZnO in OESMBIC-ZnO was found as nanorods with different lengths and diameters of 40–65 nm decorated with OESMBIC molecules. The as-prepared compounds; OESMBIC, OESMBIC-ZnO, and OESMBIC-TiO2 were used for the hydrogen storage application using the VTI method. The results prove that the addition of ZnO and TiO2 nanoparticles enhanced the storage ability of OESMBIC as the OESMBIC gave only 0.50 wt% at an equilibrium pressure of 40 bar, while it reached 2.40 and 4.37 wt% at equilibrium pressures of 60 and 75 bar for OESMBIC-ZnO and OESMBIC-TiO2, respectively.

利用 5-甲氧基-2-巯基苯并咪唑在 KOH 溶液中与氯乙酸乙酯反应,合成了 O-乙基-S-(5-甲氧基-1H-苯并[d]咪唑-2-基)硫代碳酸酯(OESMBIC)。反应产物(OESMBIC)通过傅立叶变换红外光谱(FTIR)、熔点和 1H-NMR 进行了表征。这些特征结果证明目标化合物的纯度很高。此外,工作还包括在高碱度溶液中通过化学方法合成 ZnO 和 TiO2 纳米粒子。这些纳米粒子被用来合成两种新型纳米复合材料,分别命名为 OESMBIC-ZnO 和 OESMBIC-TiO2。傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、电子衍射X射线(EDX)、电子显微镜(TEM)和X射线衍射(XRD)对合成的纳米复合材料进行了表征。结果证明,制备的氧化钛纳米管直径在 20 至 35 纳米之间,并用 OESMBIC 进行了装饰。结果证明,OESMBIC-ZnO 中的氧化锌是用 OESMBIC 分子装饰的纳米棒,其长度和直径在 40-65 纳米之间。利用 VTI 方法将制备的 OESMBIC、OESMBIC-ZnO 和 OESMBIC-TiO2 化合物用于氢气存储应用。结果证明,添加 ZnO 和 TiO2 纳米粒子增强了 OESMBIC 的储氢能力,因为 OESMBIC 在平衡压力为 40 巴时的储氢率仅为 0.50 wt%,而 OESMBIC-ZnO 和 OESMBIC-TiO2 在平衡压力为 60 巴和 75 巴时的储氢率分别达到了 2.40 wt%和 4.37 wt%。
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引用次数: 0
Performance Enhancement of Solar Still Couples With Solar Water Heater by Using Different PCM's and Nanoparticle Combinations 使用不同的 PCM 和纳米粒子组合提高太阳能热水器与太阳能蒸发器耦合的性能
Pub Date : 2024-09-11 DOI: 10.1002/est2.70023
Santosh Kumar Gupta, Devesh Kumar

The majority of the water on Earth roughly 97% is contaminated or salty, only 3% is fresh water, and only 1% of pure water is easily available for human use. In rural areas and remote locations suffering from pure drinking water scarcity.Water purification techniques are generally dependent on electricity, which relies on coal and gas plants, these poses a risk to the environment and society. Solar desalination is being recognized as the most practical way to deal with the scarcity of pure drinking water in all aspects of sustainable development. This paper describes the creation of a single slope solar still (SSSS) using opaque and crystal-clear toughened glass with a thickness of 6 mm as a cover and also another setup of a single slope phase change material (PCM)-based solar still (MSSSS). In this paper, a flat plate solar collector coupled with water heater is used to enhance the productivity of still. In this study, an experimental model has been developed to experimentally analyze exercise productivity performance of SSSS and MSSSS of MMIT Kushinagar, India on April 10, 2023 to April 15, 2023. Combination of stearic acid, lauric acid, and paraffin wax combined with CuO (nanoadditive) is used to enhance the solar still productivity. Also, basin temperature for different PCM's such as paraffin wax, lauric acid, and stearic acid are compared. Different combinations of PCM's and nanoadditives are compared to find the better productivity. It is observed that maximum output is obtained at 3:00 p.m. afternoon on experimental setup. Paraffin wax, stearic acid, and lauric acid still increases productivity by 38.8%, 20.3%, and 30.5%, respectively, when compared to simple solar still. On experimentation of various combinations, it is found that the use of PCM paraffin wax and nanoadditives CuO gives 55% better productivity compared to other combinations. This innovative system is suitable and ideal for desalinating water in isolated and rural locations with low traffic and limited demand.

地球上的大部分水(约 97% )是受污染或含盐的水,只有 3% 是淡水,只有 1% 的纯净水可供人类方便使用。在农村地区和偏远地区,纯净饮用水匮乏。水净化技术通常依赖于电力,而电力依赖于煤炭和天然气发电厂,这些都对环境和社会构成风险。在可持续发展的各个方面,太阳能海水淡化都被认为是解决纯净饮用水匮乏问题的最实用方法。本文介绍了使用厚度为 6 毫米的不透明和透明钢化玻璃作为盖板的单斜面太阳能蒸发器(SSSS),以及基于相变材料(PCM)的单斜面太阳能蒸发器(MSSSS)的另一种设置。本文使用平板太阳能集热器和热水器来提高蒸馏器的生产率。本研究开发了一个实验模型,用于实验分析印度库希纳加尔 MMIT 的 SSSS 和 MSSSS 在 2023 年 4 月 10 日至 2023 年 4 月 15 日的生产性能。硬脂酸、月桂酸和石蜡与氧化铜(纳米添加剂)的组合被用来提高太阳能蒸发器的生产率。此外,还比较了石蜡、月桂酸和硬脂酸等不同 PCM 的盆地温度。比较了 PCM 和纳米添加剂的不同组合,以找到更好的生产率。据观察,实验装置在下午 3:00 时获得最大产量。与简单的太阳能蒸馏器相比,石蜡、硬脂酸和月桂酸蒸馏器的生产率分别提高了 38.8%、20.3% 和 30.5%。在对各种组合进行实验后发现,与其他组合相比,使用 PCM 石蜡和纳米添加剂 CuO 可使生产率提高 55%。这种创新系统适用于交通不便、需求有限的偏远农村地区的海水淡化。
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引用次数: 0
Optimal Scheduling of Renewable Sources Based Micro Grid With PV and Battery Storage Using Crayfish Optimization Algorithm 使用 Crayfish 优化算法优化基于光伏和电池储能的可再生能源微电网调度
Pub Date : 2024-09-10 DOI: 10.1002/est2.70027
Subrat Bhol, Nakul Charan Sahu

Environmental concerns and energy security are pressing issues of the 21st century, with a heavy reliance on fossil fuels causing significant environmental pollution and resource depletion. To mitigate these problems, it is crucial to explore and implement alternative clean energy sources. This manuscript proposes a novel crayfish optimization algorithm (COA) for optimal scheduling in a hybrid power system that incorporates various renewable energy sources, like battery energy storage systems (BESS), fuel cells (FC), wind turbines (WT), micro turbines (MT) and photovoltaic (PV) panels. The importance of the work lies in its ability to optimize the entire operating costs of a grid-connected microgrid while improving the accuracy and efficiency of energy management. The COA method addresses economic dispatch problems and manages energy within the grid-connected microgrid, accounting for high levels of uncertainty. The proposed approach, tested using MATLAB Simulink, achieved a cost value of 252, outperforming existing methods such as GTO, PSO, SSA, and ALO. This illustrates the potential of the proposed technique to provide more cost-effective and efficient energy management solutions in hybrid power systems.

环境问题和能源安全是 21 世纪的紧迫问题,对化石燃料的严重依赖造成了严重的环境污染和资源枯竭。为了缓解这些问题,探索和实施替代性清洁能源至关重要。本手稿提出了一种新颖的小龙虾优化算法(COA),用于混合电力系统的优化调度,该系统结合了多种可再生能源,如电池储能系统(BESS)、燃料电池(FC)、风力涡轮机(WT)、微型涡轮机(MT)和光伏板(PV)。这项工作的重要性在于它能够优化并网微电网的整体运营成本,同时提高能源管理的准确性和效率。COA 方法可解决经济调度问题,并在并网微电网内管理能源,同时考虑到高度不确定性。使用 MATLAB Simulink 对所提出的方法进行了测试,其成本值为 252,优于 GTO、PSO、SSA 和 ALO 等现有方法。这说明所提出的技术有潜力为混合电力系统提供更具成本效益和效率的能源管理解决方案。
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引用次数: 0
Impacts of Adding Porous Media and Phase Change Material on Performance of Solar Water Distiller System Under Iraq Climatic Condition: An Experimental Study 伊拉克气候条件下添加多孔介质和相变材料对太阳能蒸馏水系统性能的影响:实验研究
Pub Date : 2024-09-08 DOI: 10.1002/est2.70038
Mohammed A. Basim, Omar Rafae Alomar

This current investigation involves an experimental inspection of adding porous medium and phase change material (PCM) above the absorber surface to enhance the performance of a single slope and single basin solar water distiller system. To demonstrate the effectiveness of adding porous medium and PCM, the performance of the modified system and conventional system is compared under similar operating conditions. The system that uses porous medium and PCM is called MSS-FPP, whereas the conventional system is called MSS-F. Rectangular fins are fixed above the absorber plate for both models. For MSS-FPP model, three different types of porous medium (stones, nuts, and black glass balls) are used in addition to paraffin wax filled inside circular tubes as a PCM. The data are collected in November and December 2023 in Mosul City, Iraq. The experiments are carried out under different water depths. The findings confirm that the performance of MSS-FPP model is better than MSS-F model by 41.32% (for water depth 3 cm) and 30.61% (for water depth 5 cm). The results also indicated that the water productivity of MSS-FPP model is higher than MSS-F model by 41.67% (for water depth 3 cm) and 30.65% (for water depth 5 cm). For MSS-FPP model, the maximum water productivity and efficiency are obtained when using black glass balls as compared to nuts and stones types, where the highest water temperature and water productivity values are found equal 54°C and 1.01 kg/m2 for water depth 3 cm. The enhancement in the performance of modified solar water distiller system (MSS-FPP) shows that using a porous medium and PCM has considerable impacts on the evaporation rate, heat exchange, and rate of heat transfer.

本次研究涉及在吸收器表面上方添加多孔介质和相变材料(PCM)以提高单坡单盆太阳能蒸馏器系统性能的实验检测。为了证明添加多孔介质和 PCM 的有效性,在类似的运行条件下,对改进系统和传统系统的性能进行了比较。使用多孔介质和 PCM 的系统称为 MSS-FPP,而传统系统称为 MSS-F。两种模型的吸收板上方都固定了矩形鳍片。对于 MSS-FPP 模型,除了在圆形管内填充石蜡作为 PCM 外,还使用了三种不同类型的多孔介质(石头、坚果和黑色玻璃球)。数据于 2023 年 11 月和 12 月在伊拉克摩苏尔市收集。实验在不同的水深下进行。结果证实,MSS-FPP 模型的性能比 MSS-F 模型好 41.32%(水深 3 厘米)和 30.61%(水深 5 厘米)。结果还表明,MSS-FPP 模型的水生产力比 MSS-F 模型高 41.67%(水深 3 厘米)和 30.65%(水深 5 厘米)。就 MSS-FPP 模型而言,与坚果和石头类型相比,使用黑色玻璃球可获得最高的水生产力和效率,在水深 3 厘米时,最高水温和水生产力值分别为 54°C 和 1.01 kg/m2。改良型太阳能水蒸馏器系统(MSS-FPP)性能的提高表明,使用多孔介质和 PCM 对蒸发率、热交换和传热速率有很大影响。
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引用次数: 0
Low-Temperature Annealed Fe-Doped ZnO on Bamboo-Derived Porous Carbon: High-Performance Ternary Nanocomposite for Asymmetric Supercapacitors With Superior Capacitance and Stability 竹制多孔碳上的低温退火铁掺杂氧化锌:用于不对称超级电容器的高性能三元纳米复合材料,具有卓越的电容和稳定性
Pub Date : 2024-09-06 DOI: 10.1002/est2.70037
Sivagaami Sundari Gunasekaran, Sujin P. Jose, Kumar Vediappan, Changwoo Lee, Raghu Subashchandrabose

In this study, we present a strategy of synergistic lowest-temperature annealing, and solvent-casting to synthesize Fe-doped ZnO anchored porous activated carbon-based ternary nanocomposite for asymmetric supercapacitor applications with an extended potential window of 1.2 V. The prepared nanocomposite shows a “stacked-table” like morphology with pores in the surface and walls of the carbon matrix. The incorporation of Fe-doped ZnO onto the carbon skeleton improves the conductivity by controlling morphology and specific capacitances through fast electron transfer property. The prepared nanocomposite delivers a specific capacitance of ~930 Fg−1 at 1 Ag−1. The fabricated ASC device delivers the specific capacitance of ~480 Fg−1, energy and power density of ~266.6 Whkg−1 and ~1998.5 Wkg−1 at a current of 1 and 10 Ag−1 respectively, respectively maintaining its remarkable capacitance of about 98.5% across 10 000 cycles. This superior performance can be attributed to the significant contact between the positive/negative electrode and the electrolyte which reduces the pathway of the diffused ions and enhances the conductivity of the porous carbon material aiding the electrons to travel towards the current collector. The low-temperature annealing and solvent casting strategy pave the way for the use of facile synthesis of Fe-doped ZnO as an efficient material for high-power supercapacitor applications.

在本研究中,我们采用最低温退火和溶剂浇铸的协同策略,合成了掺铁氧化锌锚定多孔活性碳三元纳米复合材料,用于扩展电位窗口(1.2 V)的不对称超级电容器应用。所制备的纳米复合材料呈现出 "叠台 "状形态,碳基质的表面和壁上都有孔隙。在碳骨架上加入掺杂铁的氧化锌,可通过控制形貌和快速电子转移特性提高比电容,从而改善导电性。所制备的纳米复合材料在 1 Ag-1 时的比电容为 ~930 Fg-1。在电流为 1 Ag-1 和 10 Ag-1 时,制备的 ASC 器件的比电容为 ~480 Fg-1,能量和功率密度分别为 ~266.6 Whkg-1 和 ~1998.5 Wkg-1,在 10 000 次循环中保持了约 98.5% 的显著电容率。这种优异的性能可归功于正/负电极与电解液之间的显著接触,这种接触减少了扩散离子的路径,并增强了多孔碳材料的导电性,有助于电子向集电极移动。低温退火和溶剂浇铸策略为方便合成掺铁氧化锌作为大功率超级电容器应用的高效材料铺平了道路。
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引用次数: 0
Investigation on Cooling Performance of Composite PCM and Graphite Fin for Battery Thermal Management System of Electric Vehicles 电动汽车电池热管理系统中 PCM 和石墨翅片复合材料冷却性能的研究
Pub Date : 2024-09-05 DOI: 10.1002/est2.70024
Nikhil S. Mane, Pradyumna Kodancha, Vadiraj Hemadri, Siddhartha Tripathi

Modern electric vehicle (EV) batteries need phase change materials (PCM) that are capable of efficient battery cooling. In this work, a composite PCM is prepared by mixing Fe3O4 nanoparticles (1 wt.%) in paraffin, and the effects of these nanoparticles on the enthalpy and melting point of PCM are studied. It is found that the Fe3O4 nanoparticle additives reduce the onset of melting from 61.46°C to 57.03°C. The composite PCM is used for the cooling of a battery module of 6 substitute-18 650 batteries, and the cooling performance is experimentally and numerically investigated. The hybrid battery thermal management system (BTMS) utilizing composite paraffin demonstrates a significant reduction of 11.2°C in lithium-ion battery (LIB) temperature compared with natural convection cooling at a heat generation rate of 2W. The numerical results in this study are in good agreement with the experimental temperature values, with a modest mean absolute error of 1.35°C detected between experimentally obtained and simulated battery temperature values. In order to deal with the low thermal conductivity of liquid PCM after PCM melting, a numerical investigation is conducted to study the effect of a graphite fin on the battery temperature. The use of a fin in hybrid BTMS considerably reduces the temperature of LIBs and temperature difference in the module. The numerical simulations capture the behavior of the phase change phenomenon, showing the evolution of liquid PCM under constant heating. This work presents the dynamic melting patterns of PCM along the length of LIB with and without a fin, which is useful for the effective design of BTMS.

现代电动汽车 (EV) 电池需要能够有效冷却电池的相变材料 (PCM)。在这项工作中,通过在石蜡中混合 Fe3O4 纳米粒子(1 wt.%)制备了一种复合 PCM,并研究了这些纳米粒子对 PCM 的焓和熔点的影响。研究发现,Fe3O4 纳米粒子添加剂可将熔点从 61.46°C 降至 57.03°C。复合 PCM 被用于冷却由 6 个替代-18 650 电池组成的电池模块,并对冷却性能进行了实验和数值研究。利用复合石蜡的混合电池热管理系统 (BTMS) 在发热量为 2W 时,与自然对流冷却相比,锂离子电池 (LIB) 温度显著降低了 11.2°C。本研究的数值结果与实验温度值十分吻合,实验温度值与模拟电池温度值之间的平均绝对误差仅为 1.35°C。针对液态 PCM 熔化后热导率较低的问题,我们进行了一项数值调查,研究石墨鳍片对电池温度的影响。在混合 BTMS 中使用石墨鳍片可大大降低 LIB 的温度和模块中的温差。数值模拟捕捉到了相变现象的行为,显示了液态 PCM 在持续加热下的演变过程。这项工作展示了有鳍片和无鳍片 LIB 沿长度方向的 PCM 动态熔化模式,有助于有效设计 BTMS。
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引用次数: 0
Optimization of Thermal Performance in Lauric Acid-Based Phase Change Materials Using a Priority Clustering Approach 利用优先聚类法优化月桂酸基相变材料的热性能
Pub Date : 2024-09-04 DOI: 10.1002/est2.70026
Osama Khan, Mohd Parvez, Pratibha Kumari, Zeinebou Yahya, Aiyeshah Alhodaib, Ashok Kumar Yadav, Anoop Kumar Shukla

This study investigates the thermal properties of lauric acid (LA) as a phase change material (PCM) using the K-Means clustering method to analyze the melting characteristics. This study focuses on the optimization of PCMs using a hybrid methodology of analytic hierarchy process (AHP) and K-Means clustering. LA, enhanced with zinc oxide (ZnO) nanoparticles, was evaluated for its thermal performance. LA's suitability as a PCM is evaluated based on initial temperature, heating rate, final temperature, and time to melt. AHP was employed to determine the weightage for three critical outcomes: latent heat, melting point, and thermal conductivity. The weightages assigned were 59%, 31%, and 11%, respectively, reflecting the relative importance of each outcome in assessing the efficiency of LA as a PCM. Furthermore, K-Means clustering was then applied to categorize the data based on these weighted outcomes. AHP was utilized to determine the weightage of input parameters, assigning 27% to initial temperature, 15% to heating rate, and 22% to final temperature, underscoring their significance in the analysis. The optimal input conditions identified were an initial temperature of 24.8°C, a ieating rate of 5.6°C/min, a final temperature of 81.4°C, and a time to melt of 10.6 min. These conditions resulted in optimal outcomes of 208 J/g for latent heat, a melting point of 80.9°C, and a thermal conductivity of 0.21 W/m·K. This hybrid approach provides a robust framework for optimizing PCM performance, facilitating enhanced thermal energy storage and release in practical applications.

本研究采用 K-Means 聚类法分析了作为相变材料 (PCM) 的月桂酸 (LA) 的熔化特性,研究了其热性能。本研究的重点是使用层次分析法(AHP)和 K-Means 聚类的混合方法优化 PCM。对添加了氧化锌(ZnO)纳米颗粒的洛杉矶进行了热性能评估。根据初始温度、加热速率、最终温度和熔化时间来评估 LA 作为 PCM 的适用性。采用 AHP 来确定潜热、熔点和热导率这三个关键结果的权重。所分配的权重分别为 59%、31% 和 11%,反映了每个结果在评估 LA 作为 PCM 的效率方面的相对重要性。然后,根据这些加权结果应用 K-Means 聚类对数据进行分类。利用 AHP 确定了输入参数的权重,其中初始温度占 27%,加热速率占 15%,最终温度占 22%,突出了它们在分析中的重要性。确定的最佳输入条件为:初始温度 24.8°C,加热速度 5.6°C/分钟,最终温度 81.4°C,熔化时间 10.6 分钟。这些条件的最佳结果是:潜热为 208 J/g,熔点为 80.9°C,导热系数为 0.21 W/m-K。这种混合方法为优化 PCM 性能提供了一个稳健的框架,有助于在实际应用中增强热能储存和释放。
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引用次数: 0
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Energy Storage
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