Fabrication of 3D-printed GNP/TiO2/epoxy composites: an investigation on mechanical and photocatalytic properties

Saadet Güler, Ahmet Yavaş, Berk Özler, A. Kılınç
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Abstract

Purpose Three-dimensional (3D) printing is popular for many applications including the production of photocatalysts. This paper aims to focus on developing of 3D-printed photocatalyst-nano composite lattice structure. Digital light processing (DLP) 3D printing of photocatalyst composites was performed using photosensitive resin mixed with 0.5% Wt. of TiO2 powder and varying amounts (0.025% Wt. to 0.2% Wt.) of graphene nanoplatelet powder. The photocatalytic efficiency of DLP 3D-printed photocatalyst TiO2 composite was investigated, and the effects of nano graphite powder incorporation on the photocatalytic activity, thermal and mechanical properties were investigated. Design/methodology/approach Methods involve 3D computer-aided design modeling, printing parameters and comprehensive characterization techniques such as structural equation modeling, X-ray diffraction, thermogravimetric analysis, Fourier-transform infrared (FTIR) and mechanical testing. Findings Results highlight successful dispersion and characteristics of TiO2 and graphene nanoplatelet (GNP) powders, intricate designs of 3D-printed lattice structures, and the influence of GNPs on thermal behavior and mechanical properties. Originality/value The study suggests applicability in wastewater treatment and environmental remediation, showcasing the adaptability of 3 D printing in designing effective photocatalysts. Future research should focus on practical applications and the long-term durability of these 3D-printed composites. Graphical abstract
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三维打印 GNP/TiO2/epoxy 复合材料的制作:机械和光催化性能研究
目的三维(3D)打印技术在包括光催化剂生产在内的许多应用领域都很受欢迎。本文旨在开发三维打印光催化剂纳米复合材料晶格结构。采用光敏树脂混合 0.5% 重量百分比的 TiO2 粉末和不同数量(0.025% 至 0.2% 重量百分比)的石墨烯纳米片粉末,对光催化剂复合材料进行了数字光处理(DLP)三维打印。研究了DLP三维打印光催化剂TiO2复合材料的光催化效率,并考察了纳米石墨粉的加入对光催化活性、热性能和机械性能的影响。设计/方法学/方法涉及三维计算机辅助设计建模、打印参数以及结构方程建模、X射线衍射、热重分析、傅立叶变换红外(FTIR)和机械测试等综合表征技术。研究结果突出了二氧化钛和石墨烯纳米板(GNP)粉末的成功分散和特性、三维打印晶格结构的复杂设计以及 GNP 对热行为和机械性能的影响。未来的研究应侧重于这些三维打印复合材料的实际应用和长期耐久性。
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