Hot Corrosion Behavior of La2Ce2O7-Based Plasma-Sprayed Coating

IF 1.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Oxidation of Metals Pub Date : 2024-04-22 DOI:10.1007/s11085-024-10244-z
S. Ariharan, Milan Parchovianský, Pushpender Singh, Pooja Rani, Rita Maurya, Anusha Sekar, Anup Kumar Keshri, Amirhossein Pakseresht
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Abstract

La2Ce2O7 (LC) has been identified as a promising thermal barrier coating (TBC) for use up to 1250 °C. In this study, a TBC system was deposited on grit-blasted Inconel 738 using atmospheric plasma spraying (APS) with NiCrAlY as the bond coat, followed by YSZ, and then LC as the top layer. The coatings were exposed to a mixture of molten Na2SO4 (45 wt.%) and V2O5 (55 wt.%) at 950 °C for hot corrosion. On the top LC layer, LaVO4, CeVO4 and CeO(1.66–2.00) formed as hot corrosion products after 4 h exposure. A reaction between YSZ and the corrosion products could not be observed due to the absence of YVO4. The hot corrosion mechanism of the LC-based TBC is also discussed in this study.

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基于 La2Ce2O7 的等离子喷涂涂层的热腐蚀行为
La2Ce2O7(LC)已被确定为一种很有前途的热障涂层(TBC),其最高使用温度可达 1250 °C。在这项研究中,采用大气等离子喷涂 (APS) 技术在经过喷砂处理的 Inconel 738 上沉积了一种 TBC 系统,以 NiCrAlY 作为结合层,然后是 YSZ,最后以 LC 作为面层。涂层在 950 °C 下暴露于熔融 Na2SO4(45 wt.%)和 V2O5(55 wt.%)的混合物中进行热腐蚀。暴露 4 小时后,在 LC 层的顶层形成了 LaVO4、CeVO4 和 CeO(1.66-2.00) 等热腐蚀产物。由于不存在 YVO4,因此无法观察到 YSZ 与腐蚀产物之间的反应。本研究还讨论了基于 LC 的 TBC 的热腐蚀机理。
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来源期刊
Oxidation of Metals
Oxidation of Metals 工程技术-冶金工程
CiteScore
5.10
自引率
9.10%
发文量
47
审稿时长
2.2 months
期刊介绍: Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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