Synthesis of carbon quantum dots based on quinoa straw and their application in alkali metal ions detection

Ye Xing, Ya-nan Wang, Haichao Li
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Abstract

Carbon quantum dots (CQDs) with good water solubility and fluorescence properties were successfully synthesized from Chenopodium quinoa Willd. straw, a biomass by-product, by a one-step carbonization method. Structural characterization of the fabricated carbon quantum dots by Fourier transform infrared spectroscopy (FT-IR) demonstrated the presence of a large number of functional groups on the surface of the carbon quantum dots, which gives them good water solubility. The synthesized carbon quantum dots were characterized optically by ultraviolet-visible absorption spectroscopy (UV-Vis), photoluminescence spectroscopy (PL), and other analytical tools. Results indicate the addition of alkali metal ions gave a different degree of promotion of fluorescence intensity (Li+>Cs+>K+>Na+>Rb+), and according to this feature carbon quantum dots can be used as a new means of alkali metal ion detection.
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基于藜麦秆的碳量子点的合成及其在碱金属离子检测中的应用
通过一步碳化法,成功地从生物质副产品藜麦秆中合成了具有良好水溶性和荧光特性的碳量子点(CQDs)。通过傅立叶变换红外光谱(FT-IR)对所制备的碳量子点进行结构表征,结果表明碳量子点表面存在大量官能团,从而使其具有良好的水溶性。通过紫外可见吸收光谱(UV-Vis)、光致发光光谱(PL)和其他分析工具对合成的碳量子点进行了光学表征。结果表明,碱金属离子的加入对荧光强度有不同程度的促进作用(Li+>Cs+>K+>Na+>Rb+),根据这一特点,碳量子点可作为一种新的碱金属离子检测手段。
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